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Shear-induced softening of nanocrystalline metal interfaces at cryogenic temperatures

Scripta Materialia

Chandross, M.; Curry, John C.; Babuska, Tomas F.; Lu, Ping L.; Furnish, Timothy A.; Kustas, Andrew K.; Nation, Brendan L.; Staats, Wayne L.; Argibay, Nicolas A.

We demonstrate inverse Hall-Petch behavior (softening) in pure copper sliding contacts at cryogenic temperatures. By kinetically limiting grain growth, it is possible to generate a quasi-stable ultra-nanocrystalline surface layer with reduced strength. In situ electrical contact resistance measurements were used to determine grain size evolution at the interface, in agreement with reports of softening in highly nanotwinned copper. We also show evidence of a direct correlation between surface grain size and friction coefficient, validating a model linking friction in pure metals and the transition from dislocation mediated plasticity to grain boundary sliding.

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Temperature-Dependent Friction and Wear Behavior of PTFE and MoS2

Tribology Letters

Babuska, Tomas F.; Pitenis, A.A.; Jones, M.R.; Nation, Brendan L.; Sawyer, W.G.; Argibay, Nicolas A.

An investigation of the temperature-dependent friction behavior of PTFE, MoS2, and PTFE-on-MoS2 is presented. Friction behavior was measured while continuously varying contact temperature in the range −150 to 175 °C while sliding in dry nitrogen, as well as for self-mated PTFE immersed in liquid nitrogen. These results contrast with previous reports of high-friction transitions and plateaus for pure and composite MoS2 at temperatures below about −20 °C; instead, we have found persistently weak thermal behavior between 0 and −196 °C, providing new insight about the molecular mechanisms of macroscale friction. The temperature-dependent friction behavior characteristic of self-mated PTFE was found also for PTFE-on-MoS2 sliding contacts, suggesting that PTFE friction was defined by subsurface deformation mechanisms and internal friction even when sliding against a lamellar lubricant with extremely low friction coefficient (µ ~ 0.02). The various relaxation temperatures of PTFE were found in the temperature-dependent friction behavior, showing excellent agreement with reported values acquired using rheological techniques measuring energy dissipation through internal friction. Additionally, hysteresis in friction behavior suggests an increase in near-surface crystallinity upon exceeding the high-temperature relaxation, Tα ~ 116 °C.

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Results 26–44 of 44
Results 26–44 of 44