Publications

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Probing water dynamics in octahedral molecular sieves: High speed 1H MAS NMR investigations

Materials Research Society Symposium Proceedings

Alam, Todd M.; Pless, Jason; Nenoff, T.M.

The water dynamics in a series of Sandia octahedral molecular sieves (SOMS) were investigated using high speed 1H magic angle spinning (MAS) NMR spectroscopy. For these materials both the 20% Ti-substituted material, Na 2Nb1.6Ti0.4(OH)0.4O 5.6·H2O and the 0% exchanged end member, Na 2Nb2O6·H2O were studied. By combining direct one dimensional (1D) MAS NMR experiments with double quantum (DQ) filtered MAS NMR experiments different water environments within the materials were identified based on differences in mobility. Two dimensional (2D) DQ correlation experiments were used to extract the DQ spinning sideband patterns allowing the residual 1H-1H homonuclear dipolar coupling to be measured. From these DQ experiments the effective order parameters for the different water environments were calculated. The water environments in the two different SOMS compositions investigated revealed very large differences in the water mobility. © 2007 Materials Research Society.

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TYPE Conference YEAR 2007
ScopusOSTI

Tools for characterizing biomembranes : final LDRD report

Alam, Todd M.; McIntyre, Sarah K.; Stevens, Mark J.

A suite of experimental nuclear magnetic resonance (NMR) spectroscopy tools were developed to investigate lipid structure and dynamics in model membrane systems. By utilizing both multinuclear and multidimensional NMR experiments a range of different intra- and inter-molecular contacts were probed within the membranes. Examples on pure single component lipid membranes and on the canonical raft forming mixture of DOPC/SM/Chol are presented. A unique gel phase pretransition in SM was also identified and characterized using these NMR techniques. In addition molecular dynamics into the hydrogen bonding network unique to sphingomyelin containing membranes were evaluated as a function of temperature, and are discussed.

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TYPE SAND Report YEAR 2007
OSTIDOI

An aqueous route to [Ta6O19]8- and solid-state studies of isostructural niobium and tantalum oxide complexes

Anderson, Travis M.; Alam, Todd M.; Rodriguez, Marko A.

Tantalate materials play a vital role in our high technology society: tantalum capacitors are found in virtually every cell phone. Furthermore, electronic characteristics and the incredibly inert nature of tantalates renders them ideal for applications such as biomedical implants, nuclear waste forms, ferroelectrics, piezoelectrics, photocatalysts and optical coatings. The inert and insoluble nature of tantalates is not fundamentally understood; and furthermore poor solubility renders fabrication of novel or optimized tantalates very difficult. We have developed a soft chemical route to water-soluble tantalum oxide clusters that can serve as both precursors for novel tantalate materials and ideal models for experimental and computational approaches to understanding the unusually inert behavior of tantalates. The water soluble cluster, [Ta6O19]8- is small, highly symmetric, and contains the representative oxygen types of a metal oxide surface, and thus ideally mimics a complex tantalate surface in a simplistic form that can be studied unambiguously. Furthermore; in aqueous solution, these highly charged and super-basic clusters orchestrate surprising acid-base behavior that most likely plays an important role in the inertness of related oxide surfaces. Our unique synthetic approach to the [Ta6O19]8- cluster allowed for unprecedented enrichment with isotopic labels (17O), enabling detailed kinetic and mechanistic studies of the behavior of cluster oxygens, as well as their acid-base behavior. This SAND report is a collection of two publications that resulted from these efforts.

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TYPE SAND Report YEAR 2007
OSTIDOI

Fuel traps: mapping stability via water association

Sabo, Dubravko S.; Greathouse, Jeffery A.; Leung, Kevin L.; Cygan, Randall T.; Alam, Todd M.; Varma, Sameer V.; Martin, Marcus G.

Hydrogen storage is a key enabling technology required for attaining a hydrogen-based economy. Fundamental research can reveal the underlying principles controlling hydrogen uptake and release by storage materials, and also aid in characterizing and designing novel storage materials. New ideas for hydrogen storage materials come from exploiting the properties of hydrophobic hydration, which refers to water s ability to stabilize, by its mode of association, specific structures under specific conditions. Although hydrogen was always considered too small to support the formation of solid clathrate hydrate structures, exciting new experiments show that water traps hydrogen molecules at conditions of low temperatures and moderate pressures. Hydrogen release is accomplished by simple warming. While these experiments lend credibility to the idea that water could form an environmentally attractive alternative storage compound for hydrogen fuel, which would advance our nation s goals of attaining a hydrogen-based economy, much work is yet required to understand and realize the full potential of clathrate hydrates for hydrogen storage. Here we undertake theoretical studies of hydrogen in water to establish a firm foundation for predictive work on clathrate hydrate H{sub 2} storage capabilities. Using molecular simulation and statistical mechanical theories based in part on quantum mechanical descriptions of molecular interactions, we characterize the interactions between hydrogen and liquid water in terms of structural and thermodynamic properties. In the process we validate classical force field models of hydrogen in water and discover new features of hydrophobic hydration that impact problems in both energy technology and biology. Finally, we predict hydrogen occupancy in the small and large cages of hydrogen clathrate hydrates, a property unresolved by previous experimental and theoretical work.

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TYPE SAND Report YEAR 2007
OSTIDOI

Bioagent detection using miniaturized NMR and nanoparticle amplification : final LDRD report

Alam, Todd M.; Adams, David P.; Williams, John D.; Fan, Hongyou F.

This LDRD program was directed towards the development of a portable micro-nuclear magnetic resonance ({micro}-NMR) spectrometer for the detection of bioagents via induced amplification of solvent relaxation based on superparamagnetic nanoparticles. The first component of this research was the fabrication and testing of two different micro-coil ({micro}-coil) platforms: namely a planar spiral NMR {micro}-coil and a cylindrical solenoid NMR {micro}-coil. These fabrication techniques are described along with the testing of the NMR performance for the individual coils. The NMR relaxivity for a series of water soluble FeMn oxide nanoparticles was also determined to explore the influence of the nanoparticle size on the observed NMR relaxation properties. In addition, The use of commercially produced superparamagnetic iron oxide nanoparticles (SPIONs) for amplification via NMR based relaxation mechanisms was also demonstrated, with the lower detection limit in number of SPIONs per nanoliter (nL) being determined.

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TYPE SAND Report YEAR 2006
OSTIDOI

Bio micro fuel cell grand challenge final report

Apblett, Christopher A.; Novak, James L.; Hudgens, James J.; Podgorski, Jason R.; Brozik, Susan M.; Flemming, Jeb H.; Ingersoll, David I.; Eisenbies, Stephen E.; Shul, Randy J.; Cornelius, Christopher J.; Fujimoto, Cy F.; Schubert, William K.; Hickner, Michael A.; Volponi, Joanne V.; Kelley, Michael J.; Zavadil, Kevin R.; Staiger, Chad S.; Dolan, Patricia L.; Harper, Jason C.; Doughty, Daniel H.; Casalnuovo, Stephen A.; Kelley, John B.; Simmons, Blake S.; Borek, Theodore T.; Meserole, Stephen M.; Alam, Todd M.; Cherry, Brian B.; Roberts, Greg

Abstract not provided.

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TYPE SAND Report YEAR 2005
OSTIDOI
Results 176–200 of 231
Results 176–200 of 231