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Evaluating the resistance of austenitic stainless steel welds to hydrogen embrittlement

American Society of Mechanical Engineers, Pressure Vessels and Piping Division (Publication) PVP

Ronevich, Joseph A.; San Marchi, Christopher W.; Balch, Dorian K.

Austenitic stainless steels are used extensively in hydrogen gas containment components due to their known resilience in hydrogen environments. Depending on the conditions, degradation can occur in austenitic stainless steels but typically the materials retain sufficient mechanical properties within such extreme environments. In many hydrogen containment applications, it is necessary or advantageous to join components through welding as it ensures minimal gas leakage, unlike mechanical fittings that can become leak paths that develop over time. Over the years many studies have focused on the mechanical behavior of austenitic stainless steels in hydrogen environments and determined their properties to be sufficient for most applications. However, significantly less data have been generated on austenitic stainless steel welds, which can exhibit more degradation than the base material. In this paper, we assess the trends observed in austenitic stainless steel welds tested in hydrogen. Experiments of welds including tensile and fracture toughness testing are assessed and comparisons to behavior of base metals are discussed.

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Technical basis for master curve for fatigue crack growth of ferritic steels in high-pressure gaseous hydrogen in ASME section VIII-3 code

American Society of Mechanical Engineers, Pressure Vessels and Piping Division (Publication) PVP

San Marchi, Christopher W.; Bortot, Paolo; Felbaum, John; Ronevich, Joseph A.; Wada, Yoru; Rana, Mahendra

The design of pressure vessels for high-pressure gaseous hydrogen service per ASME Boiler and Pressure Vessel Code Section VIII Division 3 requires measurement of fatigue crack growth rates in situ in gaseous hydrogen at the design pressure. These measurements are challenging and only a few laboratories in the world are equipped to make these measurements, especially in gaseous hydrogen at pressure in excess of 100 MPa. However, sufficient data is now available to show that common pressure vessel steels (e.g., SA-372 and SA-723) show similar fatigue crack growth rates when the maximum applied stress intensity factor is significantly less than the elastic-plastic fracture toughness. Indeed, the measured rates are sufficiently consistent that a master curve for fatigue crack growth in gaseous hydrogen can be established for steels with tensile strength less than 915 MPa. In this overview, published reports of fatigue crack growth rate data in gaseous hydrogen are reviewed. These data are used to formulate a two-part master curve for fatigue crack growth in high-pressure (106 MPa) gaseous hydrogen, following the classic power-law formulation for fatigue crack growth and a term that accounts for the loading ratio (R). The bounds on applicability of the master curve are discussed, including the relationship between hydrogen-assisted fracture and tensile strength of these steels. These data have been used in developing ASME VIII-3 Code Case 2938. Additionally, a phenomenological term for pressure can be added to the master curve and it is shown that the same master curve formulation captures the behavior of pressure vessel and pipeline steels at significantly lower pressure.

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Results 51–75 of 128
Results 51–75 of 128