Publications

Stevens, Mark J.; Bollinger, Jonathan A.; Grest, Gary S.; Rubinstein, Michael R.

Abstract not provided.

Santos, Andrew P.; Srivastava, Ishan S.; Bolintineanu, Dan S.; Lechman, Jeremy B.; Grest, Gary S.; Plimpton, Steven J.; Silbert, Leonardo E.

Abstract not provided.

Physical Review Letters

O'Connor, Thomas O.; Grest, Gary S.; Rubinstein, Michael R.

Molecular dynamics simulations confirm recent extensional flow experiments showing ring polymer melts exhibit strong extension-rate thickening of the viscosity at Weissenberg numbers Wi « 1. Thickening coincides with the extreme elongation of a minority population of rings that grows with Wi. The large susceptibility of some rings to extend is due to a flow-driven formation of topological links that connect multiple rings into supramolecular chains. Links form spontaneously with a longer delay at lower Wi and are pulled tight and stabilized by the flow. Once linked, these composite objects experience larger drag forces than individual rings, driving their strong elongation. The fraction of linked rings depends non-monotonically on Wi, increasing to a maximum when Wi 1 before rapidly decreasing when the strain rate approaches 1/T_e.

Santos, Andrew P.; Srivastava, Ishan S.; Bolintineanu, Dan S.; Leonardo, Silbert L.; Lechman, Jeremy B.; Grest, Gary S.

Abstract not provided.

Stevens, Mark J.; Bollinger, Jon B.; Grest, Gary S.; Rubinstein, Michael R.

Abstract not provided.

Grest, Gary S.

Abstract not provided.

Lane, James M.; Koski, Jason K.; Srivastava, Ishan S.; Grest, Gary S.; Ao, Tommy A.; Stoltzfus, Brian S.; Austin, Kevin N.; Fan, Hongyou F.; Morgan, Dane D.; Knudson, Marcus D.

Abstract not provided.

Physical Review E

Lechman, Jeremy B.; Bond, Stephen D.; Bolintineanu, Dan S.; Grest, Gary S.; Yarrington, Cole Y.; Silbert, Leonardo E.

Using random walk analyses we explore diffusive transport on networks obtained from contacts between isotropically compressed, monodisperse, frictionless sphere packings generated over a range of pressures in the vicinity of the jamming transition p→0. For conductive particles in an insulating medium, conduction is determined by the particle contact network with nodes representing particle centers and edges contacts between particles. The transition rate is not homogeneous, but is distributed inhomogeneously due to the randomness of packing and concomitant disorder of the contact network, e.g., the distribution of the coordination number. A narrow escape time scale is used to write a Markov process for random walks on the particle contact network. This stochastic process is analyzed in terms of spectral density of the random, sparse, Euclidean and real, symmetric, positive, semidefinite transition rate matrix. Results show network structures derived from jammed particles have properties similar to ordered, euclidean lattices but also some unique properties that distinguish them from other structures that are in some sense more homogeneous. In particular, the distribution of eigenvalues of the transition rate matrix follow a power law with spectral dimension 3. However, quantitative details of the statistics of the eigenvectors show subtle differences with homogeneous lattices and allow us to distinguish between topological and geometric sources of disorder in the network.

Journal of Physical Chemistry C

Srivastava, Ishan S.; Peters, Brandon L.; Lane, J.M.; Fan, Hongyou F.; Salerno, K.M.; Grest, Gary S.

Pressure-driven assembly of ligand-grafted gold nanoparticle superlattices is a promising approach for fabricating gold nanostructures, such as nanowires and nanosheets. Optimizing this fabrication method will require extending our understanding of superlattice mechanics to regimes of high pressures. We use molecular dynamics simulations to characterize the response of alkanethiol-grafted gold nanoparticle superlattices to applied hydrostatic pressures up to 15 GPa. At low applied pressures, intrinsic voids govern the mechanics of compaction. As applied pressures increase, the void collapse and ligand compression depend significantly on the ligand length. These microstructural observations correlate directly with trends in bulk modulus and elastic constants. For short ligands, core-core contact between gold nanoparticles is observed at high pressures, which augurs irreversible response and eventual sintering. This presintering behavior was unexpected under hydrostatic loading and is observed only for the shortest ligands.

Journal of Chemical Physics

Tang, Yanfei; Grest, Gary S.; Cheng, Shengfeng

Large scale molecular dynamics simulations are used to study drying suspensions of a binary mixture of large and small particles in explicit and implicit solvents. The solvent is first modeled explicitly and then mapped to a uniform viscous medium by matching the diffusion coefficients and the pair correlation functions of the particles. "Small-on-top" stratification of the particles, with an enrichment of the smaller ones at the receding liquid-vapor interface during drying, is observed in both models under the same drying conditions. With the implicit solvent model, we are able to model much thicker films and study the effect of the initial film thickness on the final distribution of particles in the dry film. Our results show that the degree of stratification is controlled by the Péclet number defined using the initial film thickness as the characteristic length scale. When the Péclet numbers of large and small particles are much larger than 1, the degree of "small-on-top" stratification is first enhanced and then weakens as the Péclet numbers are increased.

Srivastava, Ishan S.; Grest, Gary S.; Silbert, Leonardo E.; Lechman, Jeremy B.

Abstract not provided.

Srivastava, Ishan S.; Grest, Gary S.; Silbert, Leonardo E.; Lechman, Jeremy B.

Abstract not provided.

Santos, Andrew P.; Srivastava, Ishan S.; Bolintineanu, Dan S.; Lechman, Jeremy B.; Silbert, Leonard E.; Grest, Gary S.

Abstract not provided.

Srivastava, Ishan S.; Grest, Gary S.; Lechman, Jeremy B.; Silbert, Leonardo E.

Abstract not provided.

Lechman, Jeremy B.; Srivastava, Ishan S.; Bolintineanu, Dan S.; Grest, Gary S.

Abstract not provided.

O'Connor, Thomas O.; Grest, Gary S.; Ge, Ting G.; Rubinstein, Michael R.

Abstract not provided.

Srivastava, Ishan S.; Peters, Brandon L.; Lane, James M.; Fan, Hongyou F.; Grest, Gary S.; Salerno, Michael S.

Pressure-driven assembly of ligand-grafted gold nanoparticle superlattices is a promising approach for fabricating gold nanostructures, such as nanowires and nanosheets. However, optimizing this fabrication method requires an understanding of the mechanics of their complex hierarchical assemblies at high pressures. We use molecular dynamics simulations to characterize the response of alkanethiol-grafted gold nanoparticle superlattices to applied hydrostatic pressures up to 15 GPa, and demonstrate that the internal mechanics significantly depend on ligand length. At low pressures, intrinsic voids govern the mechanics of pressure-induced compaction, and the dynamics of collapse of these voids under pressure depend significantly on ligand length. These microstructural observations correlate well with the observed trends in bulk modulus and elastic constants. For the shortest ligands at high pressures, coating failure leads to gold core-core contact, an augur of irreversible response and eventual sintering. This behavior was unexpected under hydrostatic loading, and was only observed for the shortest ligands.

Journal of Chemical Physics

Wijesinghe, Sidath; Perahia, Dvora; Grest, Gary S.

The temperature response of luminescent ionizable polymers confined into far from equilibrium nanoparticles without chemical links was studied using molecular dynamics simulations. These nanoparticles, often referred to as polydots, are emerging as a promising tool for nanomedicine. Incorporating ionizable groups into these polymers enables biofunctionality; however, they also affect the delicate balance of interactions that hold these nanoparticles together. Here polydots formed by a model polymer dialkyl p-phenylene ethynylene with varying number of carboxylate groups along the polymer backbone were probed. We find that increasing temperature affects neutral and charged polydots differently, where neutral polydots exhibit a transition above which their structure becomes dynamic and they unravel. The dependence of the transition temperature on the surface to volume ratio of these polydots is much stronger than what has previously been observed in polymeric thin films. Charged polydots become dynamic enabling migration of the ionizable groups toward the particle interface, while retaining the overall particle shape.

Physical Review Letters

Peters, Brandon L.; Salerno, K.M.; Ge, Ting; Perahia, Dvora; Grest, Gary S.

While nearly all theoretical and computational studies of entangled polymer melts have focused on uniform samples, polymer synthesis routes always result in some dispersity, albeit narrow, of distribution of molecular weights (Crossed D signM=Mw/Mn∼1.02-1.04). Here, the effects of dispersity on chain mobility are studied for entangled, disperse melts using a coarse-grained model for polyethylene. Polymer melts with chain lengths set to follow a Schulz-Zimm distribution for the same average Mw=36 kg/mol with Crossed D signM=1.0 to 1.16, were studied for times of 600-800 μs using molecular dynamics simulations. This time frame is longer than the time required to reach the diffusive regime. We find that dispersity in this range does not affect the entanglement time or tube diameter. However, while there is negligible difference in the average mobility of chains for the uniform distribution Crossed D signM=1.0 and Crossed D signM=1.02, the shortest chains move significantly faster than the longest ones offering a constraint release pathway for the melts for larger Crossed D signM.

Lechman, Jeremy B.; Bolintineanu, Dan S.; Grillet, Anne M.; Srivastava, Ishan S.; Grest, Gary S.

Abstract not provided.

Srivastava, Ishan S.; Silbert, Leonardo E.; Lechman, Jeremy B.; Grest, Gary S.

Abstract not provided.

Grest, Gary S.; Salerno, K.M.; Peters, Brandon L.; Ge, Ting G.; Perahia, Dvora P.

Abstract not provided.

Langmuir

Tang, Yanfei; Grest, Gary S.; Cheng, Shengfeng

Large scale molecular dynamics simulations for bidisperse nanoparticle suspensions with an explicit solvent are used to investigate the effects of evaporation rates and volume fractions on the nanoparticle distribution during drying. Our results show that "small-on-top" stratification can occur when Pesøs ≳ c with c ∼ 1, where Pes is the Péclet number and øs is the volume fraction of the smaller particles. This threshold of Pesøs for "small-on-top" is larger by a factor of ∼α2 than the prediction of the model treating solvent as an implicit viscous background, where α is the size ratio between the large and small particles. Our simulations further show that when the evaporation rate of the solvent is reduced, the "small-on-top" stratification can be enhanced, which is not predicted by existing theories. This unexpected behavior is explained with thermophoresis associated with a positive gradient of solvent density caused by evaporative cooling at the liquid/vapor interface. For ultrafast evaporation the gradient is large and drives the nanoparticles toward the liquid/vapor interface. This phoretic effect is stronger for larger nanoparticles, and consequently the "small-on-top" stratification becomes more distinct when the evaporation rate is slower (but not too slow such that a uniform distribution of nanoparticles in the drying film is produced), as thermophoresis that favors larger particles on the top is mitigated. A similar effect can lead to "large-on-top" stratification for Pesøs above the threshold when Pes is large but øs is small. Our results reveal the importance of including the solvent explicitly when modeling evaporation-induced particle separation and organization and point to the important role of density gradients brought about by ultrafast evaporation.

Srivastava, Ishan S.; Grest, Gary S.; Lechman, Jeremy B.; Silbert, Leonardo E.

Abstract not provided.

Peters, Brandon L.; Grest, Gary S.

Abstract not provided.