Publications

Spoerke, Erik D.; Wheeler, Jill S.; Brown-Shaklee, Harlan J.; Ihlefeld, Jon I.; Blea-Kirby, Mia A.; Small, Leo J.; Johnson, Linda E.; Waldrip, Karen W.

Abstract not provided.

Materials Research Society Symposium Proceedings

Alam, Todd M.; Bell, Nelson S.; Wheeler, Jill; Spoerke, Erik D.; Cygan, Randall T.; Ingersoll, David I.

High temperature solid state sodium (23Na) magic angle spinning (MAS) NMR spin lattice relaxation times (T1) were evaluated for a series of NASICON (Na3Zr2PS12O12) materials to directly determine Na jump rates. Simulations of the Ti temperature variations that incorporated distributions in Na jump activation energies, or distribution of jump rates, improved the agreement with experiment. The 23Na NMR T1 relaxation results revealed that distributions in the Na dynamics were present for all of the NASICON materials investigated here. The 23Na relaxation experiments also showed that small differences in material composition and/or changes in the processing conditions impacted the distributions in the Na dynamics. The extent of the distribution was related to the presence of a disordered or glassy phosphate phase present in these different sol-gel processed materials. The 23Na NMR T1 relaxation experiments are a powerful tool to directly probing Na jump dynamics and provide additional molecular level details that could impact transport phenomena.

Ihlefeld, Jon I.; Kotula, Paul G.; Lu, Ping L.; McKenzie, Bonnie B.; Allen, Amy A.; Rye, Michael J.; Gough, Dara G.; Spoerke, Erik D.; Blea-Kirby, Mia A.; Brown-Shaklee, Harlan J.; Gauntt, Brian G.; Shelton, Christopher T.; Brennecka, Geoffrey L.; Meyer, Kelsey E.

Abstract not provided.

Martinez, Alina M.; Jones, Brad H.; Spoerke, Erik D.; Wheeler, Jill S.

Abstract not provided.

Jones, Brad H.; Martinez, Alina M.; Wheeler, Jill S.; McKenzie, Bonnie B.; Wheeler, David R.; Spoerke, Erik D.

Abstract not provided.

Ingersoll, David I.; Spoerke, Erik D.; Domino, Stefan P.; Hewson, John C.; Clem, Paul G.; Kee, Prof.R.; Porter, Prof.J.; Wachsman, Prof.E.; Bhavaraju, S.B.; Zhu, H.Z.; Jolley, A.J.; Robins, M.R.

Abstract not provided.

Spoerke, Erik D.; Wheeler, Jill S.; Ihlefeld, Jon I.; Blea-Kirby, Mia A.; Brown-Shaklee, Harlan J.; Rodriguez, Mark A.

Abstract not provided.

Vandelinder, Virginia A.; Wheeler, David R.; Small, Leo J.; Spoerke, Erik D.; Henderson, Ian M.; Bachand, George B.

Abstract not provided.

Allendorf, Mark D.; Azoulay, Jason A.; Ford, Alexandra C.; Foster, Michael E.; El Gabaly Marquez, Farid E.; Leonard, Francois L.; Leong, Kirsty; Stavila, Vitalie S.; Talin, A.A.; Wong, Brian M.; Brumbach, Michael T.; Van Gough, D.V.; Lambert, Timothy N.; Rodriguez, Mark A.; Spoerke, Erik D.; Wheeler, David R.; Deaton, Joseph C.; Centrone, Andrea C.; Haney, Paul H.; Kinney, R.K.; Szalai, Veronika S.; Yoon, Heayoung P.

Electro-optical organic materials hold great promise for the development of high-efficiency devices based on exciton formation and dissociation, such as organic photovoltaics (OPV) and organic light-emitting devices (OLEDs). However, the external quantum efficiency (EQE) of both OPV and OLEDs must be improved to make these technologies economical. Efficiency rolloff in OLEDs and inability to control morphology at key OPV interfaces both reduce EQE. Only by creating materials that allow manipulation and control of the intimate assembly and communication between various nanoscale excitonic components can we hope to first understand and then engineer the system to allow these materials to reach their potential. The aims of this proposal are to: 1) develop a paradigm-changing platform for probing excitonic processes composed of Crystalline Nanoporous Frameworks (CNFs) infiltrated with secondary materials (such as a complimentary semiconductor); 2) use them to probe fundamental aspects of excitonic processes; and 3) create prototype OPVs and OLEDs using infiltrated CNF as active device components. These functional platforms will allow detailed control of key interactions at the nanoscale, overcoming the disorder and limited synthetic control inherent in conventional organic materials. CNFs are revolutionary inorganic-organic hybrid materials boasting unmatched synthetic flexibility that allow tuning of chemical, geometric, electrical, and light absorption/generation properties. For example, bandgap engineering is feasible and polyaromatic linkers provide tunable photon antennae; rigid 1-5 nm pores provide an oriented, intimate host for triplet emitters (to improve light emission in OLEDs) or secondary semiconducting polymers (creating a charge-separation interface in OPV). These atomically engineered, ordered structures will enable critical fundamental questions to be answered concerning charge transport, nanoscale interfaces, and exciton behavior that are inaccessible in disordered systems. Implementing this concept also creates entirely new dimensions for device fabrication that could both improve performance, increase durability, and reduce costs with unprecedented control of over properties. This report summarizes the key results of this project and is divided into sections based on publications that resulted from the work. We begin in Section 2 with an investigation of light harvesting and energy transfer in a MOF infiltrated with donor and acceptor molecules of the type typically used in OPV devices (thiophenes and fullerenes, respectively). The results show that MOFs can provide multiple functions: as a light harvester, as a stabilizer and organizer or the infiltrated molecules, and as a facilitator of energy transfer. Section 3 describes computational design of MOF linker groups to accomplish light harvesting in the visible and facilitate charge separation and transport. The predictions were validated by UV-visible absorption spectroscopy, demonstrating that rational design of MOFs for light-harvesting purposes is feasible. Section 4 extends the infiltration concept discussed in Section to, which we now designate as "Molecule@MOF" to create an electrically conducting framework. The tailorability and high conductivity of this material are unprecedented, meriting publication in the journal Science and spawning several Technical Advances. Section 5 discusses processes we developed for depositing MOFs as thin films on substrates, a critical enabling technology for fabricating MOF-based electronic devices. Finally, in Section 6 we summarize results showing that a MOF thin film can be used as a sensitizer in a DSSC, demonstrating that MOFs can serve as active layers in excitonic devices. Overall, this project provides several crucial proofs-of- concept that the potential of MOFs for use in optoelectronic devices that we predicted several years ago [ 3 ] can be realized in practice.

Spoerke, Erik D.; Bell, Nelson S.; Edney, Cynthia E.; Wheeler, Jill S.; Cygan, Randall T.; Alam, Todd M.; Ihlefeld, Jon I.; Clem, Paul G.; Ingersoll, David I.

Abstract not provided.

Journal of Physical Chemistry B

Ting, Christina L.; Frischknecht, Amalie F.; Stevens, Mark J.; Spoerke, Erik D.

Electrostatics plays an important role in the self-assembly of amphiphilic peptides. To develop a molecular understanding of the role of the electrostatic interactions, we develop a coarse-grained model peptide and apply self-consistent field theory to investigate the peptide assembly into a variety of aggregate nanostructures. We find that the presence and distribution of charged groups on the hydrophilic branches of the peptide can modify the molecular configuration from extended to collapsed. This change in molecular configuration influences the packing into spherical micelles, cylindrical micelles (nanofibers), or planar bilayers. The effects of charge distribution therefore have important implications for the design and utility of functional materials based on peptides. © 2014 American Chemical Society.

Powder Diffraction

Rodriguez, Marko A.; Brown-Shaklee, Harlan J.; Blea-Kirby, Mia A.; Ihlefeld, Jon I.; Spoerke, Erik D.

Abstract not provided.

Spoerke, Erik D.; Wolf, Steven W.; Wheeler, Jill S.; Gough, Dara G.; Lambert, Timothy N.; Foster, Michael E.; Leong, Kirsty; Stavila, Vitalie S.; Allendorf, Mark D.

Abstract not provided.

Spoerke, Erik D.

Abstract not provided.

Spoerke, Erik D.; Ihlefeld, Jon I.; Brown-Shaklee, Harlan J.; Rodriguez, Marko A.; Wheeler, Jill S.; Blea-Kirby, Mia A.

Abstract not provided.

Journal of Chemical Education

Spoerke, Erik D.; Small, Leo J.; Wolf, Steven W.

Abstract not provided.

Frischknecht, Amalie F.; Stevens, Mark J.; Spoerke, Erik D.

Abstract not provided.

Small, Leo J.; Spoerke, Erik D.; Wolf, Steven W.; Vandelinder, Virginia A.; Bachand, George B.

Abstract not provided.

Spoerke, Erik D.; Bell, Nelson S.; Edney, Cynthia E.; Wheeler, Jill S.; Small, Leo J.; Ingersoll, David I.

Abstract not provided.

Spoerke, Erik D.; Gough, Dara G.; Wheeler, Jill S.; Lambert, Timothy N.; Stavila, Vitalie S.; Allendorf, Mark D.

Abstract not provided.

Small, Leo J.; Spoerke, Erik D.; Wolf, Steven W.; Bachand, George B.; Vandelinder, Virginia A.

Abstract not provided.

Spoerke, Erik D.; Bell, Nelson S.; Edney, Cynthia E.; Wheeler, Jill S.

Abstract not provided.

Ihlefeld, Jon I.; Allen, Amy A.; Kotula, Paul G.; Brennecka, Geoffrey L.; Gough, Dara G.; Spoerke, Erik D.; Brown-Shaklee, Harlan J.; Lu, Ping L.; Blea-Kirby, Mia A.; McKenzie, Bonnie B.

Abstract not provided.

Spoerke, Erik D.; Wheeler, Jill S.; Gough, Dara G.; Foster, Michael E.; Leong, Kirsty; Allendorf, Mark D.; Stavila, Vitalie S.; Lambert, Timothy N.; Wolf, Steven W.

Abstract not provided.

Cygan, Randall T.; Spoerke, Erik D.

Abstract not provided.