Publications

Medlin, Douglas L.

Abstract not provided.

Karnesky, Richard A.; Medlin, Douglas L.; Hattar, Khalid M.; Bufford, Daniel C.; Koh, A.K.; Lawrence, Samantha K.; Somerday, Brian P.

Abstract not provided.

Abdeljawad, Fadi F.; Medlin, Douglas L.; Zimmerman, Jonathan A.; Hattar, Khalid M.; Foiles, Stephen M.

Abstract not provided.

Philosophical Magazine

O'Brien, Christopher J.; Medlin, Douglas L.; Foiles, Stephen M.

Grain boundary-engineered materials are of immense interest for their corrosion resistance, fracture resistance and microstructural stability. This work contributes to a larger goal of understanding both the structure and thermodynamic properties of grain boundaries vicinal (within) to the (coherent twin) boundary which is found in grain boundary-engineered materials. The misoriented boundaries vicinal to the twin show structural changes at elevated temperatures. In the case of nickel, this transition temperature is substantially below the melting point and at temperatures commonly reached during processing, making the existence of such boundaries very likely in applications. Thus, the thermodynamic stability of such features is thoroughly investigated in order to predict and fully understand the structure of boundaries vicinal to twins. Low misorientation angle grain boundaries () show distinct disconnections which accommodate misorientation in opposite senses. The two types of disconnection have differing lowerature structures which show different temperature-dependent behaviours with one type undergoing a structural transition at approximately 600 K. At misorientation angles greater than approximately, the discrete disconnection nature is lost as the disconnections merge into one another. Free energy calculations demonstrate that these high-angle boundaries, which exhibit a transition from a planar to a faceted structure, are thermodynamically more stable in the faceted configuration.

Medlin, Douglas L.

Abstract not provided.

Spataru, Dan C.; Thurmer, Konrad T.; Leonard, Francois L.; Medlin, Douglas L.; He, Yuping H.

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Medlin, Douglas L.

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Abdeljawad, Fadi F.; Medlin, Douglas L.; Zimmerman, Jonathan A.; Hattar, Khalid M.; Foiles, Stephen M.

Abstract not provided.

Abdeljawad, Fadi F.; Medlin, Douglas L.; Zimmerman, Jonathan A.; Hattar, Khalid M.; Foiles, Stephen M.

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Abdeljawad, Fadi F.; Medlin, Douglas L.; Hattar, Khalid M.; Zimmerman, Jonathan A.; Foiles, Stephen M.

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Siegal, Michael P.; Friedman, Caitlin R.; Sharma, Peter A.; Medlin, Douglas L.

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APL Materials

Rochford, C.; Medlin, Douglas L.; Erickson, K.J.; Siegal, Michael P.

Compositional-homogeneity and crystalline-orientation are necessary attributes to achieve high thermoelectric performance in Bi1-xSbx thin films. Following deposition in vacuum, and upon air exposure, we find that 50%-95% of the Sb in 100-nm thick films segregates to form a nanocrystalline Sb2O3 surface layer, leaving the film bulk as Bi-metal. However, we demonstrate that a thin SiN capping layer deposited prior to air exposure prevents Sb-segregation, preserving a uniform film composition. Furthermore, the capping layer enables annealing in forming gas to improve crystalline orientations along the preferred trigonal axis, beneficially reducing electrical resistivity.

Ihlefeld, Jon I.; Scrymgeour, David S.; Paisley, Elizabeth A.; Medlin, Douglas L.; McKenzie, Bonnie B.; Michael, Joseph R.; Johnson, Raegan L.; Foley, Brian M.; Wallace, Margeaux W.; Trolier-McKinstry, Susan T.; Hopkins, Patrick E.

Abstract not provided.

Abdeljawad, Fadi F.; Medlin, Douglas L.; Zimmerman, Jonathan A.; Hattar, Khalid M.; Foiles, Stephen M.

Abstract not provided.

Abdeljawad, Fadi F.; Medlin, Douglas L.; Zimmerman, Jonathan A.; Hattar, Khalid M.; Foiles, Stephen M.

Abstract not provided.

Zimmerman, Jonathan A.; Medlin, Douglas L.; Abdeljawad, Fadi F.; Hattar, Khalid M.; Foiles, Stephen M.

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Medlin, Douglas L.

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Medlin, Douglas L.

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Ihlefeld, Jon I.; Scrymgeour, David S.; Michael, Joseph R.; McKenzie, Bonnie B.; Medlin, Douglas L.; Blea-Kirby, Mia A.; Foley, Brian M.; Hopkins, Patrick E.; Wallace, Margeaux W.; Trolier-McKinstry, Susan T.

Abstract not provided.

Abdeljawad, Fadi F.; Medlin, Douglas L.; Zimmerman, Jonathan A.; Hattar, Khalid M.; Foiles, Stephen M.

Abstract not provided.

Ihlefeld, Jon I.; Foley, Brian M.; Medlin, Douglas L.; McKenzie, Bonnie B.; Michael, Joseph R.; Scrymgeour, David S.; Wallace, Margeaux W.; Trolier-McKinstry, Susan T.; Hopkins, Patrick E.

Abstract not provided.

Scrymgeour, David S.; Ihlefeld, Jon I.; Michael, Joseph R.; McKenzie, Bonnie B.; Foley, Brian M.; Hopkins, Patrick E.; Medlin, Douglas L.

Abstract not provided.

Nano Letters

Ihlefeld, Jon I.; Foley, Brian M.; Scrymgeour, David S.; Michael, Joseph R.; McKenzie, Bonnie B.; Medlin, Douglas L.; Wallace, Margeaux; Trolier-Mckinstry, Susan; Hopkins, Patrick E.

Dynamic control of thermal transport in solid-state systems is a transformative capability with the promise to propel technologies including phononic logic, thermal management, and energy harvesting. A solid-state solution to rapidly manipulate phonons has escaped the scientific community. We demonstrate active and reversible tuning of thermal conductivity by manipulating the nanoscale ferroelastic domain structure of a Pb(Zr0.3Ti0.7)O3 film with applied electric fields. With subsecond response times, the room-temperature thermal conductivity was modulated by 11%.

Applied Physics Letters

Sharma, P.A.; Lima Sharma, A.L.; Hekmaty, Michelle A.; Hattar, K.; Stavila, Vitalie S.; Goeke, R.; Erickson, K.; Medlin, Douglas L.; Brahlek, M.; Koirala, N.; Oh, S.

We demonstrate chemical doping of a topological insulator Bi2Se3 using ion implantation. Ion beam-induced structural damage was characterized using grazing incidence X-ray diffraction and transmission electron microscopy. Ion damage was reversed using a simple thermal annealing step. Carrier-type conversion was achieved using ion implantation followed by an activation anneal in Bi2Se3 thin films. These two sets of experiments establish the feasibility of ion implantation for chemical modification of Bi2Se3, a prototypical topological insulator. Ion implantation can, in principle, be used for any topological insulator. The direct implantation of dopants should allow better control over carrier concentrations for the purposes of achieving low bulk conductivity. Ion implantation also enables the fabrication of inhomogeneously doped structures, which in turn should make possible new types of device designs.

Journal of the American Ceramic Society

Foley, Brian M.; Brown-Shaklee, Harlan J.; Campion, Michael J.; Medlin, Douglas L.; Clem, Paul G.; Ihlefeld, Jon I.; Hopkins, Patrick E.

We have measured the cross-plane thermal conductivity (κ) of (010)-textured, undoped, and lanthanum-doped strontium niobate (Sr2-xLaxNb2O7-δ) thin films via time-domain thermoreflectance. The thin films were deposited on (001)-oriented SrTiO3 substrates via the highly-scalable technique of chemical solution deposition. We find that both film thickness and lanthanum doping have little effect on κ, suggesting that there is a more dominant phonon scattering mechanism present in the system; namely the weak interlayer-bonding along the b-axis in the Sr2Nb2O7 parent structure. Furthermore, we compare our experimental results with two variations of the minimum-limit model for κ and discuss the nature of transport in material systems with weakly-bonded layers. The low cross-plane κ of these scalably-fabricated films is comparable to that of similarly layered niobate structures grown epitaxially.