Publications

Kuhlman, Kristopher L.; Brady, Patrick V.; Sassani, David C.; Freeze, Geoffrey A.; Hardin, Ernest H.

Abstract not provided.

Freeze, Geoffrey A.; Brady, Patrick V.; Sassani, David C.; Kuhlman, Kristopher L.

Abstract not provided.

Freeze, Geoffrey A.; Arnold, Bill W.; Brady, Patrick V.; Sassani, David C.; Kuhlman, Kristopher L.; MacKinnon, R.J.; Hardin, Ernest H.

Abstract not provided.

Sassani, David C.; Hardin, Ernest H.; Kuhlman, Kristopher L.; MacKinnon, R.J.

The amount of brine present in domal salt formation is far less than in bedded salts (e.g., 0.01 to 0.1% compared with 1 to 3%). In salt domes, shear deformation associated with diapirism has caused existing brine to coalesce, leading to flow and expulsion. Brine migration behavior was investigated in bedded salt at WIPP (Nowak and McTigue 1987, SAND87-0880), and in domal salt at Asse (Coyle et al. 1987, BMI/ONWI-624). Test methods were not standardized, and the tests involved large diameter boreholes (17 to 36 in. diameter) and large apparatus. The tested intervals were proximal to mined openings (within approximately 1 diameter) where in situ stresses are redistributed due to excavation. The tests showed that (1) brine inflow rates can range over at least 2 orders of magnitude for domal vs. bedded salt, (2) that brine inflow is strongly associated with clay and interbedded permeable layers in bedded salt, and (3) that measurement systems can readily collect very small quantities of moisture over time frames of 2 years or longer. Brine inflow rates declined slightly with time in both test series, but neither series approached a state of apparent depletion. This range of flow magnitude could be significant to repository design and performance assessment, especially if inflow rates can be predicted using stratigraphic and geomechanical inputs, and can be shown to approach zero in a predictable manner.

15th International High-Level Radioactive Waste Management Conference 2015, IHLRWM 2015

Kuhlman, Rristopher L.; Arnold, Bill W.; Brady, Patrick V.; Sassani, David C.; Freeze, Geoffrey A.; Hardin, Ernest H.

Deep Borehole Disposal (DBD) of radioactive waste has some clear advantages over mined repositories, including incremental construction and loading, enhanced natural barriers provided by deep continental crystalline basement, and reduced site characterization. Unfavorable features for a DBD site include upward vertical fluid potential gradients, presence of economically exploitable natural resources, presence of high permeability connection from the waste disposal zone to the shallow subsurface, and significant probability of future volcanic activity. Site characterization activities would encompass geomechanical (i.e., rock stress state, fluid pressure, and faulting), geological (i.e., both overburden and bedrock lithology), hydrological (i.e., quantity of fluid, fluid convection properties, and solute transport mechanisms), chemical (i.e., rock and fluid interaction), and socioeconomic (i.e., likelihood for human intrusion) aspects. For a planned Deep Borehole Field Test (DBFT), site features and/or physical processes would be evaluated using both direct (i.e., sampling and in-hole testing) and indirect (i.e., surface and borehole geophysical) methods for efficient and effective characterization. Surface-based characterization would be used to guide the exploratory drilling program, once a candidate DBFT site has been selected. Borehole based characterization will be used to determine the variability of system state (i.e., stress, pressure, temperature, petrology, and water chemistry) with depth, and to develop material and system parameters relevant for numerical simulation. While the site design of DBD could involve an array of disposal boreholes, it may not be necessary to characterize each borehole in detail. Characterization strategies will be developed in the DBFT that establish disposal system safety sufficient for licensing a disposal array.

15th International High-Level Radioactive Waste Management Conference 2015, IHLRWM 2015

Brady, Patrick V.; Arnold, Bill W.; MacKinnon, R.J.; Hardin, Ernest H.; Sassani, David C.; Kuhlman, Kristopher L.; Freeze, Geoffrey A.

While deep borehole disposal of nuclear waste should rely primarily on off-the-shelf technologies pioneered by the oil and gas and geothermal industries, the development of new science and technology will remain important. Key knowledge gaps have been outlined in the research roadmap for deep boreholes (B. Arnold et al, 2012, Research, Development, and Demonstration Roadmap for Deep Borehole Disposal, Sandia National Laboratories, SAND2012-8527P) and in a recent Deep Borehole Science Needs Workshop. Characterizing deep crystalline basement, understanding the nature and role of deep fractures, more precisely age-dating deep groundwaters, and demonstrating long-term performance of seals are all important topics of interest. Overlapping deep borehole and enhanced geothermal technology needs include: quantification of seal material performance/failure, stress measurement beyond the borehole, advanced drilling and completion tools, and better subsurface sensors. A deep borehole demonstration has the potential to trigger more focused study of deep hydrology, high temperature brine-rock interaction, and thermomechanical behavior.

Freeze, Geoffrey A.; Arnold, Bill W.; Brady, Patrick V.; Sassani, David C.; Kuhlman, Kristopher L.; MacKinnon, R.J.

Abstract not provided.

15th International High-Level Radioactive Waste Management Conference 2015, IHLRWM 2015

Price, Laura L.; Sassani, David C.; Swift, Peter N.; Bonano, Evaristo J.

Options for disposal of the spent nuclear fuel and high level radioactive waste that are projected to exist in the United States in 2048 were studied. The options included four different disposal concepts: mined repositories in salt, clay/shale rocks, and crystalline rocks; and deep boreholes in crystalline rocks. Some of the results of this study are that all waste forms, with the exception of untreated sodium-bonded spent nuclear fuel, can be disposed of in any of the mined disposal concepts, although with varying degrees of confidence; salt allows for more flexibility in managing high-heat waste in mined repositories than other media; small waste forms are potentially attractive candidates for deep borehole disposal; and disposal of commercial SNF in existing dual-purpose canisters is potentially feasible but could pose significant challenges both in repository operations and in demonstrating confidence in long-term performance. Questions addressed by this study include: is a " 'one-size-fits-all ' repository a good strategic option for disposal?" and "do some disposal concepts perform significantly better with or without specific waste types or forms? " The study provides the bases for answering these questions by evaluating potential impacts of waste forms on the feasibility and performance of representative generic concepts for geologic disposal.

Freeze, Geoffrey A.; Arnold, Bill W.; Brady, Patrick V.; Sassani, David C.; Kuhlman, Kristopher L.

Abstract not provided.

Price, Laura L.; Sassani, David C.; Swift, Peter N.; Bonano, Evaristo J.

Abstract not provided.

Sassani, David C.; Kuhlman, Kristopher L.

Abstract not provided.

Sassani, David C.

Abstract not provided.

Sassani, David C.

Abstract not provided.

Mariner, Paul M.; Sassani, David C.

An analysis of the Waste Isolation Pilot Plant (WIPP) colloid model constraints and parameter values was performed. The focus of this work was primarily on intrinsic colloids, mineral fragment colloids, and humic substance colloids, with a lesser focus on microbial colloids. Comments by the US Environmental Protection Agency (EPA) concerning intrinsic Th(IV) colloids and Mg-Cl-OH mineral fragment colloids were addressed in detail, assumptions and data used to constrain colloid model calculations were evaluated, and inconsistencies between data and model parameter values were identified. This work resulted in a list of specific conclusions regarding model integrity, model conservatism, and opportunities for improvement related to each of the four colloid types included in the WIPP performance assessment.

Sassani, David C.; Weck, Philippe F.

Abstract not provided.

Sassani, David C.; Jove Colon, Carlos F.; Weck, Philippe F.

Abstract not provided.

Mariner, Paul M.; Sassani, David C.

Abstract not provided.

Sassani, David C.; Jove Colon, Carlos F.

Abstract not provided.

Proposed for publication in Reliability Engineering and System Safety.

Hansen, Clifford H.; Olszewska-Wasiolek, Maryla A.; Bryan, Charles R.; Hardin, Ernest H.; Jarek, Russell L.; Mariner, Paul M.; Mattie, Patrick D.; Sassani, David C.; Sevougian, Stephen D.; Stein, Joshua S.

Abstract not provided.

Weck, Philippe F.; Jove Colon, Carlos F.; Sassani, David C.

Abstract not provided.

Sassani, David C.; Jove Colon, Carlos F.; Weck, Philippe F.

Abstract not provided.

Jove Colon, Carlos F.; Sassani, David C.

Abstract not provided.

Dalton Transactions

Weck, Philippe F.; Kim, Eunja; Jove Colon, Carlos F.; Sassani, David C.

The structures of the only known minerals containing peroxide, namely studtite [(UO 2)O 2(H 2O) 4] and metastudtite [(UO 2)O 2(H 2O) 2], have been investigated using density functional theory. The structure of metastudtite crystallizing in the orthorhombic space group Pnma (Z = 4) is reported for the first time at the atomic level and the computed lattice parameters, a = 8.45, b = 8.72, c = 6.75 Å, demonstrate that the unit cell of metastudtite is larger than previously reported dimensions (Z = 2) derived from experimental X-ray powder diffraction data. © 2012 The Royal Society of Chemistry.

Sassani, David C.

Abstract not provided.

Hansen, Francis D.; Wang, Yifeng; Sassani, David C.

Abstract not provided.