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Unconventional peroxy chemistry in alcohol oxidation: The water elimination pathway

Journal of Physical Chemistry Letters

Welz, Oliver W.; Klippenstein, Stephen J.; Harding, Lawrence B.; Taatjes, Craig A.; Zador, Judit Z.

Predictive simulation for designing efficient engines requires detailed modeling of combustion chemistry, for which the possibility of unknown pathways is a continual concern. Here, we characterize a low-lying water elimination pathway from key hydroperoxyalkyl (QOOH) radicals derived from alcohols. The corresponding saddle-point structure involves the interaction of radical and zwitterionic electronic states. This interaction presents extreme difficulties for electronic structure characterizations, but we demonstrate that these properties of this saddle point can be well captured by M06-2X and CCSD(T) methods. Experimental evidence for the existence and relevance of this pathway is shown in recently reported data on the low-temperature oxidation of isopentanol and isobutanol. In these systems, water elimination is a major pathway, and is likely ubiquitous in low-temperature alcohol oxidation. These findings will substantially alter current alcohol oxidation mechanisms. Moreover, the methods described will be useful for the more general phenomenon of interacting radical and zwitterionic states. © 2013 American Chemical Society.

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TYPE Conference YEAR 2013
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Low-temperature combustion chemistry of biofuels: Pathways in the low-temperature (550-700 K) oxidation chemistry of isobutanol and tert-butanol

Proceedings of the Combustion Institute

Welz, Oliver W.; Savee, John D.; Eskola, Arkke J.; Sheps, Leonid S.; Osborn, David L.; Taatjes, Craig A.

Butanol isomers are promising next-generation biofuels. Their use in internal combustion applications, especially those relying on low-temperature autoignition, requires an understanding of their low-temperature combustion chemistry. Whereas the high-temperature oxidation chemistry of all four butanol isomers has been the subject of substantial experimental and theoretical efforts, their low-temperature oxidation chemistry remains underexplored. In this work we report an experimental study on the fundamental low-temperature oxidation chemistry of two butanol isomers, tert-butanol and isobutanol, in low-pressure (4-5.1 Torr) experiments at 550 and 700 K. We use pulsed-photolytic chlorine atom initiation to generate hydroxyalkyl radicals derived from tert-butanol and isobutanol, and probe the chemistry of these radicals in the presence of an excess of O2 by multiplexed time-resolved tunable synchrotron photoionization mass spectrometry. Isomer-resolved yields of stable products are determined, providing insight into the chemistry of the different hydroxyalkyl radicals. In isobutanol oxidation, we find that the reaction of the a-hydroxyalkyl radical with O2 is predominantly linked to chain-terminating formation of HO2. The Waddington mechanism, associated with chain-propagating formation of OH, is the main product channel in the reactions of O2 with b-hydroxyalkyl radicals derived from both tert-butanol and isobutanol. In the tert-butanol case, direct HO2 elimination is not possible in the b-hydroxyalkyl + O2 reaction because of the absence of a beta C-H bond; this channel is available in the b-hydroxyalkyl + O2 reaction for isobutanol, but we find that it is strongly suppressed. Observed evolution of the main products from 550 to 700 K can be qualitatively explained by an increasing role of hydroxyalkyl radical decomposition at 700 K. © 2012 The Combustion Institute. Published by Elsevier Inc. All rights reserved.

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TYPE Journal Article YEAR 2013
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Results 101–125 of 222
Results 101–125 of 222