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In situ TEM ion irradiation and atmospheric heating of cladding materials

Materials Research Society Symposium Proceedings

Hattar, K.; Rajasekhara, Shreyas R.; Clark, Blythe C.

Over the course of use, both in-service and during storage, fuel claddings for nuclear reactors undergo complex changes that can drastically change their material properties. Exposures to irradiation, temperature changes, and stresses, as well as contact with coolant, storage pool, and dry storage environments, may induce microstructural changes, such as formation of radiation defects, precipitate dissolution, and chemical segregation, that can ultimately result in failure of the cladding if pushed beyond its limit. In order to predict the performance of cladding in-service and during storage, understanding of the dominant processes related to these changes and their consequences is essential. In situ transmission electron microscopy (TEM) allows dynamic observation, at the nanoscale, of microstructural changes under a range of stimuli, making it an excellent tool for deepening our understanding of microstructural evolution in claddings. This proceeding presents details of the new in situ ion irradiation TEM and in situ gas cell TEM capabilities developed at Sandia National Laboratories. In addition, it will present the initial results from both systems investigating radiation tolerance of potential Generation IV cladding materials and understanding degradation mechanisms in Zr-based claddings of importance for dry storage. © 2012 Materials Research Society.

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The hardness and strength of metal tribofilms: An apparent contradiction between nanoindentation and pillar compression

Acta Materialia

Battaile, Corbett C.; Boyce, Brad L.; Weinberger, Christopher R.; Prasad, Somuri V.; Michael, Joseph R.; Clark, Blythe C.

After sliding contact of a hard spherical counterface on a metal surface, the resulting wear scar possesses a complex microstructure consisting of dislocations, dislocation cells, ultrafine or nanocrystalline grains, and material that has undergone dynamic recovery. There remains a controversy as to the mechanical properties of the tribolayer formed in this wear scar. To investigate the properties of this thin layer of damaged material in single crystal nickel, we employed two complementary techniques: pillar compression and nanoindentation. In both techniques, the tests were tailored to characterize the near surface properties associated with the top 500 nm of material, where the wear-induced damage was most extensive. Pillar compression indicated that the worn material was substantially softer than neighboring unworn base metal. However, nanoindentation showed that the wear track was substantially harder than the base metal. These apparently contradictory results are explained on the basis of source limited deformation. The worn pillars are softer than unworn pillars due to a pre-straining effect: undefected pillars are nearly free of dislocations, whereas worn pillars have pre-existing dislocations built in. Nanoindentation in worn material behaves harder than unworn single crystal nickel due to source length reduction from the fine-grained wear structure. © 2011 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

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Results 76–100 of 124
Results 76–100 of 124