Publications

Proposed for publication in Journal of the American Chemical Society.

Tian, Zhengrong R.; Voigt, James A.; McKenzie, Bonnie B.

We report for the first time a one-step, templateless method to directly prepare large arrays of oriented TiO{sub 2}-based nanotubes and continuous films. These titania nanostructures can also be easily prepared as conformal coatings on a substrate. The nanostructured films were formed on a Ti substrate seeded with TiO{sub 2} nanoparticles. SEM and TEM results suggested that a folding mechanism of sheetlike structures was involved in the formation of the nanotubes. The oriented arrays of TiO{sub 2} nanotubes, continuous films, and coatings are expected to have potentials for applications in catalysis, filtration, sensing, photovoltaic cells, and high surface area electrodes.

Nano Letters

Tian, Zhengrong R.; Liu, Jun; Xu, Huifang; Voigt, James A.; McKenzie, Bonnie B.; Matzke, C.M.

This paper reports the preparation of cubically ordered, self-assembled nanostructural crystals on micropatterned surfaces. Large ordered arrays of octahedral crystals were formed on substrates with triangular-shaped micropatterns that match the shape of the {111} surface morphology of the crystals. Many crystals became self-aligned in X, Y, and Z orientations through the interaction with the matching micropatterns. However, line micropatterns did not produce such well-defined crystals and crystal alignment. This work is among the first examples to show 3D crystal alignment independent of the long rodlike micellar structure that is characteristic of the hexagonal phases. Significantly, it also suggests that the geometry of the underline patterns has a large effect on the crystal morphology and orientation. We hope that these results will be helpful in developing microdevices based on self-assembled nanoscale materials.

Proposed for publication in JACS or Nature Materials.

Tian, Zhengrong R.; Voigt, James A.; McKenzie, Bonnie B.; Mcdermott, Matthew M.; Rodriguez, Marko A.; Cygan, Randall T.; Criscenti, Louise C.

Abstract not provided.