Exploiting the Tailorable Nanoporosity of Metal-Organic Frameworks for In-Situ Identification of Radioisotopes
Abstract not provided.
Publications
Increasing the optical transmittance via decreasing crystallite dimensions?insights on MOF luminescence sensing applications
Abstract not provided.
Metal-Organic Frameworks for Catalytic Biomass Upgrading : Investigation of C?C Bond Formation by Aldol Condensation in a Pre-Defined Pore Space
Abstract not provided.
Soup to Nuts: MOFs for Production Transport and Storage of Fuels
Abstract not provided.
Exploiting MOF Luminosity and Porosity for In-Situ Detection of Xenon Isotopes
Abstract not provided.
Electrolyte-Assisted Hydrogen Storage Reactions
Journal of Physical Chemistry C
Use of electrolytes, in the form of LiBH4/KBH4 and LiI/KI/CsI eutectics, is shown to significantly improve (by more than a factor of 10) both the dehydrogenation and full rehydrogenation of the MgH2/Sn destabilized hydride system and the hydrogenation of MgB2 to Mg(BH4)2. The improvement revealed that interparticle transport of atoms heavier than hydrogen can be an important rate-limiting step during hydrogen cycling in hydrogen storage materials consisting of multiple phases in powder form. Electrolytes enable solubilizing heavy ions into a liquid environment and thereby facilitate the reaction over full surface areas of interacting particles. The examples presented suggest that use of electrolytes in the form of eutectics, ionic liquids, or solvents containing dissolved salts may be generally applicable for increasing reaction rates in complex and destabilized hydride materials.
Role of Surface Oxidation in the Dehydrogenation of Complex Metal Hydrides
Abstract not provided.
Exploiting MOF Luminosity and Porosity for In-Situ Detection of Radioisotopes
Abstract not provided.
8 Results