Publications

Brennecka, Amanda L.; Moore, Roger H.; Sanchez, Margaret S.; Hutchinson, Michael A.

Abstract not provided.

Brennecka, Amanda L.; Moore, Roger H.; Sanchez, Margaret S.; Hutchinson, Michael A.

Abstract not provided.

Brennecka, Amanda L.; Moore, Roger H.; Hutchinson, Michael A.; Sanchez, Margaret S.

Abstract not provided.

Yang, Pin Y.; Roesler, Alexander R.; Moore, Roger H.; DiAntonio, Christopher D.; Montgomery, Stephen M.

Abstract not provided.

Brennecka, Amanda L.; Moore, Roger H.; Sanchez, Margaret S.; Hutchinson, Michael A.; Roesler, Alexander R.

Abstract not provided.

Yang, Pin Y.; Roesler, Alexander R.; Moore, Roger H.; DiAntonio, Christopher D.; Montgomery, Stephen M.

Structural phase transformations between ferroelectric (FE), antiferroelectric (AFE), and paraelectric (FE) phases are frequently observed in the zirconia-rich phase region on the lead zirconate-titanate (PZT) phase diagram. Since the free energy difference among these phases is small, phase transformation can be easily induced by temperature, pressure and electric field. These induced transformation characteristics have been used for many practical applications. This study focuses on a hydrostatic pressure induced FE-to-AFE phase transformation in a tin modified PZT ceramic (PSZT). The relative phase stability between FE and AFE phases is determined by the dielectric permittivity measurement as a function of temperature from -60 C to 125 C. A pressure-temperature phase diagram for the PSZT system will be presented.

Grubbs, Robert K.; Roesler, Alexander R.; Moore, Roger H.; DiAntonio, Christopher D.; Montgomery, Stephen M.

Phase transformation between the ferroelectric (FE) and the antiferroelectric (AFE) phases in tin modified lead zirconate titanate (PSZT) ceramics can be influenced by pressure and electric field. Increasing the pressure has the tendency to favor the AFE phase while electric field favors the FE phase. In this study, these phase transformations are studied as functions of external pressure, temperature, and dc bias. The shifting of transformation temperature and the relative phase stability between FE and AFE with respect to these external parameters will be presented. Results will be compared to a pressure-induced depoling behavior (or FE-to-AFE phase transformation) for the PSZT ceramic. Fundamental issues relates to the relative phase stability will be discussed from the perspective of lattice dynamics theory.

Brennecka, Amanda L.; Moore, Roger H.; Hutchinson, Michael A.; Roesler, Alexander R.; Sanchez, Margaret S.

Abstract not provided.

Moore, Roger H.; Hutchinson, Michael A.; Yang, Pin Y.; Zschiesche, Dale Z.

Abstract not provided.

Hutchinson, Michael A.; Moore, Roger H.; Roesler, Alexander R.; Zschiesche, Dale Z.

Pb-based ferroelectrics are useful because of their large dielectric constants, high polarization values, and strong piezoelectric coefficients, but typically require sintering temperatures >1200 C, which leads to loss of the volatile Pb cation and necessitates the use of Pt electrodes for cofired parts. Reduced sintering temperatures can minimize lead loss and enable the use of cheaper electrodes, but must not sacrifice electrical performance. A systematic study of dopants to lower the sintering temperature of PNSZT (Pb0.992 (Zr0.815 Ti0.05 Sn0.135)0.9845 Nb0.155 O3) led to densities greater than 98.5% of theoretical at temperatures as low as 1100 C with as little as 0.2 wt% of a Pb glass additive or as high as 98% at 900 C with Cu2O additions with equivalent electrical properties to undoped materials.

Brennecka, Amanda L.; Moore, Roger H.; Zschiesche, Dale Z.; Hutchinson, Michael A.; Roesler, Alexander R.

Abstract not provided.

Moore, Roger H.; Hutchinson, Michael A.; Yang, Pin Y.; Zschiesche, Dale Z.

Abstract not provided.

Moore, Roger H.; Hutchinson, Michael A.; Yang, Pin Y.; Zschiesche, Dale Z.

Abstract not provided.

Moore, Roger H.

Abstract not provided.

Ceramic Engineering and Science Proceedings

Yang, Pin; Voigt, James A.; Rodriguez, Marko A.; Moore, Roger H.; Burns, George B.

The impacts of small niobium additions to processing, microstructure, and electrical properties in the Zr-rich lead zirconate titanate ceramics (PZT 95/5) were investigated. The influence of niobium content on dielectric responses and the characteristics of ferroelectric behaviors, as well as the relative phase stability and the hydrostatic pressure induced ferroelectric-to- antiferroelectric phase transformation are reported. Results indicate that increasing the niobium concentration in the solid solutions enhances densification, refines the microstructure, decreases dielectric constant and spontaneous polarization, and stabilizes the ferroelectric phase. The stabilization of ferroelectric phase with respect to the antiferroelectric phase near PZT 95/5 composition dramatically increases the pressure required for the ferroelectric-to-antiferroelectric phase transformation. These observations were correlated to the creation of A-site vacancies and a slight modification of the crystal structure. The importance of these composition-property relationships on device application will be presented.

Moore, Roger H.; Moore, Roger H.; Montoya, Ted V.; Spindle, Thomas L.

Chemical synthesis methods are being developed as a future source of PZT 95/5 powder for neutron generator voltage bar applications. Laboratory-scale powder processes were established to produce PZT billets from these powders. The interactions between calcining temperature, sintering temperature, and pore former content were studied to identify the conditions necessary to produce PZT billets of the desired density and grain size. Several binder systems and pressing aids were evaluated for producing uniform sintered billets with low open porosity. The development of these processes supported the powder synthesis efforts and enabled comparisons between different chem-prep routes.

Yang, Pin Y.; Yang, Pin Y.; Moore, Roger H.; Lockwood, Steven J.; Tuttle, Bruce T.; Voigt, James A.; Scofield, Timothy W.

The hydrostatically induced ferroelectric(FE)-to-antiferroelectric(AFE) phase transformation for chemically prepared niobium modified PZT 95/5 ceramics was studied as a function of density and pore former type (Lucite or Avicel). Special attention was placed on the effect of different pore formers on the charge release behavior associated with the FE-to-AFE phase transformation. Within the same density range (7.26 g/cm3 to 7.44 g/cm3), results showed that ceramics prepared with Lucite pore former exhibit a higher bulk modulus and a sharper polarization release behavior than those prepared with Avicel. In addition, the average transformation pressure was 10.7% greater and the amount of polarization released was 2.1% higher for ceramics with Lucite pore former. The increased transformation pressure was attributed to the increase of bulk modulus associated with Lucite pore former. Data indicated that a minimum volumetric transformational strain of -0.42% was required to trigger the hydrostatically induced FE-to-AFE phase transformation. This work has important implications for increasing the high temperature charge output for neutron generator power supply units.

Sipola, Diana L.; Sipola, Diana L.; Voigt, James A.; Watson, Chad S.; McKenzie, Bonnie B.; Moore, Roger H.; Hutchinson, Michael A.; Lockwood, Steven J.; Wright, Emily D.

The Materials Chemistry Department 1846 has developed a lab-scale chem-prep process for the synthesis of PNZT 95/5, referred to as the ''SP'' process (Sandia Process). This process (TSP) has been successfully transferred to and scaled-up by Department 14192 (Ceramics and Glass Department), producing the larger quantities of PZT powder required to meet the future supply needs of Sandia for neutron generator production. The particle size distributions of TSP powders routinely have been found to contain a large particle size fraction that was absent in development (SP) powders. This SAND report documents experimental studies focused on characterizing these particles and assessing their potential impact on material performance. To characterize these larger particles, fractionation of several TSP powders was performed. The ''large particle size fractions'' obtained were characterized by particle size analysis, SEM, and ICP analysis and incorporated into compacts and sintered. Large particles were found to be very similar in structure and composition as the bulk of the powder. Studies showed that the large-size fractions of the powders behave similarly to the non-fractionated powder with respect to the types of microstructural features once sintered. Powders were also compared that were prepared using different post-synthesis processing (i.e. differences in precipitate drying). Results showed that these powders contained different amounts and sizes of porous inclusions when sintered. How this affects the functional performance of the PZT 95/5 material is the subject of future investigations.