Optical fiber diagnostics are extensively used in pulsed power experiments, such as the Sandia Z machine. However, radiation produced in a pulsed power environment can significantly affect these measurements. Catastrophic fiber darkening may be mitigated with shielding, but no flexible material can stop all radiation produced by the machine and/or target. Radiation-induced refractive index modulations are particularly challenging for optical interferometry. Several approaches for radiation-tolerant photonic Doppler velocimetry are discussed here.
Thermal spray processes involve the repeated impact of millions of discrete particles, whose melting, deformation, and coating-formation dynamics occur at microsecond timescales. The accumulated coating that evolves over minutes is comprised of complex, multiphase microstructures, and the timescale difference between the individual particle solidification and the overall coating formation represents a significant challenge for analysts attempting to simulate microstructure evolution. In order to overcome the computational burden, researchers have created rule-based models (similar to cellular automata methods) that do not directly simulate the physics of the process. Instead, the simulation is governed by a set of predefined rules, which do not capture the fine-details of the evolution, but do provide a useful approximation for the simulation of coating microstructures. Here, we introduce a new rules-based process model for microstructure formation during thermal spray processes. The model is 3D, allows for an arbitrary number of material types, and includes multiple porosity-generation mechanisms. Example results of the model for tantalum coatings are presented along with sensitivity analyses of model parameters and validation against 3D experimental data. The model's computational efficiency allows for investigations into the stochastic variation of coating microstructures, in addition to the typical process-to-structure relationships.
Phenolic polymers are key components in carbon composites used in heat shielding due to their ablative properties, and are oftentimes exposed to extreme conditions such as heating and shock. Our ability to model these systems requires an understanding of shock induced chemical pathways. In this work, three parametrizations of the ReaxFF classical MD potential are compared in their ability to model phenolic polymers under shock induced chemistry. We calculate the activation energies associated with both the formation of water, and the liberation of volatile compounds via an Arrhenius analysis of several constant temperature pyrolysis simulations. The activation energies for all three parametrizations are in agreement with the experimental thermogravimetric analysis (TGA) results. We also study phenol, a relevant model system with a well-defined structure. We compare the density of phenol, for temperatures ranging from 123 K to 423 K. The accuracy of the density of phenol at various temperatures serves as an indicator for the ability of a given parametrization to predict density of a phenolic polymer under shock.
The equation of state (EOS) of bulk niobium (Nb) was investigated within the framework of density functional theory, with Mermin's generalization to finite temperatures. The shock Hugoniot for fully-dense and porous Nb was obtained from canonical ab initio molecular dynamics simulations with Erpenbeck's approach based on the Rankine-Hugoniot jump conditions. The phase space was sampled along isotherms between 300 and 4000 K, for densities ranging from ρ=5.5 to 12 g/cm3. Results from simulations compare favorably with room-temperature multianvil and diamond anvil cell data for fully-dense Nb samples and with a recent tabulated SESAME EOS. The results of this study indicate that, for the application of weak and intermediate shocks, the tabular EOS models are expected to give reliable predictions.
Thermal degradation of polyethylene is studied under the extremely high rate temperature ramps expected in laser-driven and X-ray ablation experiments - from 1010 to 1014 K/s in isochoric, condensed phases. The molecular evolution and macroscopic state variables are extracted as a function of density from reactive molecular dynamics simulations using the ReaxFF potential. The enthalpy, dissociation onset temperature, bond evolution, and observed cross-linking are shown to be rate dependent. These results are used to parametrize a kinetic rate model for the decomposition and coalescence of hydrocarbons as a function of temperature, temperature ramp rate, and density. The results are contrasted to first-order random-scission macrokinetic models often assumed for pyrolysis of linear polyethylene under ambient conditions.
Double-shell Ar gas puff implosions driven by 16.5 ± 0.5 MA on the Z generator at Sandia National Laboratories are very effective emitters of Ar K-shell radiation (photon energy >3 keV), producing yields of 330 ± 9% kJ [B. Jones et al., Phys. Plasmas 22, 020706 (2015)]. Previous simulations and experiments have reported dramatic increases in K-shell yields when adding an on-axis jet to double shell gas puffs for some configurations. We report on a series of experiments on Z testing Ar gas puff configurations with and without an on-axis jet guided by 3D magneto-hydrodynamic (MHD) simulations. Adding an on-axis jet was found to significantly improve the performance of some, but not all, configurations. The maximum observed K-shell yield of 375 ± 9% kJ was produced with a configuration that rapidly imploded onto an on-axis jet. A dramatic difference was observed in the plasma conditions at stagnation when a jet was used, producing a narrower stagnation column in experiments with a higher density but relatively lower electron temperature. The MHD simulations accurately reproduce the experimental measurements. The conversion efficiency for electrical energy delivered to the load to K-shell x-rays is estimated to be ∼12.5% for the best-performing configuration, similar to the best results from experiments at smaller facilities.
By varying current-loss circuit parameters, the Mach2-tabular collisional radiative equilibrium 2-D radiation magnetohydrodynamic model was tuned to reproduce the radiative and electrical properties of three recent argon gas-puff experiments (same initial conditions) performed on the Z machine at Sandia National Laboratories. The model indicates that there were current losses occurring near or within the diode region of the Z machine during the stagnation phase of the implosion. The 'good' simulation reproduces the experimental K-shell powers, K-shell yields, total powers, percentage of emission radiated in α lines, size of the K-shell emission region, and the average electron temperature near the time-of-peak K-shell power. The calculated atomic populations, ion temperatures, and radial velocities are used as input to a detailed multifrequency ray-trace radiation transport model that includes the Doppler effect. This model is employed to construct time-, space-, and energy-resolved synthetic spectra. The role the Doppler effect likely plays in the experiments is demonstrated by comparing synthetic spectra generated with and without this effect.
Argon gas puffs have produced 330kJ ± 9% of x-ray radiation above 3keV photon energy in fast z-pinch implosions, with remarkably reproducible K-shell spectra and power pulses. This reproducibility in x-ray production is particularly significant in light of the variations in instability evolution observed between experiments. Soft x-ray power measurements and K-shell line ratios from a time-resolved spectrum at peak x-ray power suggest that plasma gradients in these high-mass pinches may limit the K-shell radiating mass, K-shell power, and K-shell yield from high-current gas puffs.
This report summarizes the work completed under the Laboratory Directed Research and Development (LDRD) project 10-0973 of the same title. Understanding the molecular origin of the no-slip boundary condition remains vitally important for understanding molecular transport in biological, environmental and energy-related processes, with broad technological implications. Moreover, the viscoelastic properties of fluids in nanoconfinement or near surfaces are not well-understood. We have critically reviewed progress in this area, evaluated key experimental and theoretical methods, and made unique and important discoveries addressing these and related scientific questions. Thematically, the discoveries include insight into the orientation of water molecules on metal surfaces, the premelting of ice, the nucleation of water and alcohol vapors between surface asperities and the lubricity of these molecules when confined inside nanopores, the influence of water nucleation on adhesion to salts and silicates, and the growth and superplasticity of NaCl nanowires.