New aircraft are being designed with increasing quantities of composite materials used in their construction. Different from the more traditional metals, composites have a higher propensity to burn. This presents a challenge to transportation safety analyses, as the aircraft structure now represents an additional fuel source involved in the fire scenario. Performance testing data for composites burning in a fire at the integral scales of an accident event are nearly non-existent. This report describes fire tests for relevant carbon fiber epoxy materials that were designed to explore the bulk decomposition behavior of said material in a severe fire. Together with TGA decomposition data, the material is found to decompose in three mostly distinctive and sequential phases, epoxy pyrolysis, char oxidation, and carbon fiber oxidation. Fires were not severe in their thermal intensity compared to liquid fuel fires. Peak thermal intensities of around 220 kW/m2 or 1100 °C are achieved at very low air flow rates. The burn tests were remarkable in their duration, lasting 4-8 hours for 25-40 kg of combustible material.
Composite materials behave differently from conventional fuel sources and have the potential to smolder and burn for extended time periods. As the amount of composite materials on modern aircraft continues to increase, understanding the response of composites in fire environments becomes increasingly important. An effort is ongoing to enhance the capability to simulate composite material response in fires including the decomposition of the composite and the interaction with a fire. To adequately model composite material in a fire, two physical model development tasks are necessary; first, the decomposition model for the composite material and second, the interaction with a fire. A porous media approach for the decomposition model including a time dependent formulation with the effects of heat, mass, species, and momentum transfer of the porous solid and gas phase is being implemented in an engineering code, ARIA. ARIA is a Sandia National Laboratories multiphysics code including a range of capabilities such as incompressible Navier-Stokes equations, energy transport equations, species transport equations, non-Newtonian fluid rheology, linear elastic solid mechanics, and electro-statics. To simulate the fire, FUEGO, also a Sandia National Laboratories code, is coupled to ARIA. FUEGO represents the turbulent, buoyantly driven incompressible flow, heat transfer, mass transfer, and combustion. FUEGO and ARIA are uniquely able to solve this problem because they were designed using a common architecture (SIERRA) that enhances multiphysics coupling and both codes are capable of massively parallel calculations, enhancing performance. The decomposition reaction model is developed from small scale experimental data including thermogravimetric analysis (TGA) and Differential Scanning Calorimetry (DSC) in both nitrogen and air for a range of heating rates and from available data in the literature. The response of the composite material subject to a radiant heat flux boundary condition is examined to study the propagation of decomposition fronts of the epoxy and carbon fiber and their dependence on the ambient conditions such as oxygen concentration, surface flow velocity, and radiant heat flux. In addition to the computational effort, small scaled experimental efforts to attain adequate data used to validate model predictions is ongoing. The goal of this paper is to demonstrate the progress of the capability for a typical composite material and emphasize the path forward.
Polymer foams are used as encapsulants to provide mechanical, electrical, and thermal isolation for engineered systems. In fire environments, the incident heat flux to a system or structure can cause foams to decompose. Commonly used foams, such as polyurethanes, often liquefy and flow during decomposition, and evolved gases can cause pressurization and ultimately failure of sealed containers. In systems safety and hazard analyses, numerical models are used to predict heat transfer to encapsulated objects or through structures. The thermo-mechanical response of systems involving coupled foam decomposition, liquefaction, and flow can be difficult to predict. Predicting pressurization of sealed systems is particularly challenging. To mitigate the issues caused by liquefaction and flow, hybrid polyurethane cyanate ester foams have been developed that have good adhesion and mechanical properties similar to currently used polyurethane and epoxy foams. The hybrid foam decomposes predictably during decomposition. It forms approximately 50 percent by weight char during decomposition in nitrogen. The foam does not liquefy. The charring nature of the hybrid foam has several advantages with respect to modeling heat transfer and pressurization. Those advantages are illustrated by results from recent radiant heat transfer experiments involving encapsulated objects, as well as results from numerical simulations of those experiments.
Thermal gravimetric analysis (TGA) combined with evolved gas analysis by Fourier transform infrared spectroscopy (FTIR) or mass spectrometry (MS) often is used to study thermal decomposition of organic polymers. Frequently, results are used to determine decomposition mechanisms and to develop rate expressions for a variety of applications, which include hazard analyses. Although some current TGA instruments operate with controlled heating rates as high as 500° C/min, most experiments are done at much lower heating rates of about 5° to 50° C/min to minimize temperature gradients in the sample. The intended applications, such as hazard analyses involving fire environments, for rate expressions developed from TGA experiments often involve heating rates much greater than 50° C/min. The heating rate can affect polymer decomposition by altering relative rates at which competing decomposition reactions occur. Analysis of the effect of heating rate on competing first-order decomposition reactions with Arrhenius rate constants indicated that relative to heating rates of 5° to 50° C/min, observable changes in decomposition behavior may occur when heating rates approach 1,000° C/min. Results from experiments with poly(methyl methacrylate) (PMMA) samples that were heated at 5° to 50° C/min during TGA-FTIR experiments and results from experiments with samples heated at rates on the order of 1,000° C/min during pyrolysis-GC-FTIR experiments supported the analyses.
The investigation of the liquefaction and flow behavior of a thermally decomposing removable epoxy foam (REF) was discussed. It was concluded that the behavior of REF, can vary greatly depending on both physical and thermal boundary conditions as well as on decomposition chemistry. It was shown that the foam regression away from a heated surface generally involves two moving boundaries, a fluid-solid interface and a fluid-vapor interface. During thermal decomposition, the physical and chemical behaviors of the foams were coupled and can significantly affect heat transfer rates to the encapsulated units.