Publications

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As supercritical carbon dioxide (sCO2) is emerging as a potential working fluid in power production Brayton cycles, fluid purity within the power cycle loops has become an issue impacting commercialization. Sandia National Laboratories has been evaluating the longevity of sCO2 recompression closed Brayton power cycles to quantify the advantages of sCO2 over other fluids as utilizing sCO2 yields comparatively greater efficiencies. Hydrocarbon plugging has been observed in the small printed circuit heat exchanger channels of our high temperature recuperator, increasing pressure drop across the heat exchanger. As pressure drop is a critical factor in the overall efficiency of sCO2 recompression closed Brayton cycles, in this paper we report on our investigation into heat exchanger efficiency reduction from hydrocarbon plugging induced pressure drop.

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The Sandia S-CO₂ Recompression Closed Brayton Cycle (RCBC) utilizes a series of gas foil bearings in its turbine-alternator-compressors. At high shaft rotational speed these bearings allow the shaft to ride on a cushion of air. Conversely, during startup and shutdown, the shaft rides along the foil bearing surface. Low-friction coatings are used on bearing surfaces in order to facilitate rotation during these periods. An experimental program was initiated to elucidate the behavior of coated bearing foils in the harsh environments of this system. A test configuration was developed enabling long duration exposure tests, followed by a range of analyses relevant to their performance in a bearing. This report provides a detailed overview of this work. The results contained herein provide valuable information in selecting appropriate coatings for more advanced future bearing-rig tests at the newly established test facility in Sandia-NM.

The supercritical carbon dioxide (S - CO2) Brayton Cycle has gained significant attention in the last decade as an advanced power cycle capab le of achieving high efficiency power conversion. Sandia National Laboratories, with support from the U.S. Department of Energy Office of Nuclear Energy (US DOE - NE), has been conducting research and development in order to deliver a technology that is rea dy for commercialization. There are a wide range of materials related challenges that must be overcome for the success of this technology. At Sandia, recent work has focused on the following main areas: (1) Investigating the potential for system cost re duction through the introduction of low cost alloys in low temperature loop sections, (2) Identifying material options for 10MW RCBC systems, (3) Understanding and resolving turbine degradation, (4) Identifying gas foil bearing behavior in CO 2 , and (5) Ide ntifying the influence of gas chemistry on alloy corrosion. Progress in each of these areas is provided in this report.

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At Sandia National Laboratories (SNL), The Nuclear Energy Systems Laboratory / Brayton Lab has been established to research and develop subsystems and demonstrate the viability of the closed Brayton cycles (CBC), and in particular, the recompression CBC. The ultimate objective of this program is to have a commercial-ready system available for small modular reactors. For this objective, R&D efforts must demonstrate that, among other things, component and the system behavior is understood and control is manageable, and system performance is predictable. Research activities that address these needs include investigating system responses to various anticipated perturbations, and demonstrating that component and system performance is understood. To these ends, this paper presents system response to a perturbation, and turbomachinery performance results during steady state operation. A long duration test, with an extensive period at steady state, was completed in the simple CBC configuration. During this period, a cooling perturbation was initiated. Data from this test are presented and evaluated to explain the sequence of events following the perturbation. It was found that a cascading series of events ensued, starting with the fluid condensing effect of the cooling perturbation. The explanation of events emphasizes the highly interactive and nonlinear nature of CBC's. The comparisons of measured and predicted turbomachinery performance yielded excellent results and give confidence that the predictive methods originally envisioned for this system work well.

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Digital image correlation (DIC) uses images from a camera and lens system to make quantitative measurements of the shape, displacement, and strain of test objects. This increasingly popular method has had little research on the influence of the imaging system resolution on the DIC results. This paper investigates the entire imaging system and studies how both the camera and lens resolution influence the DIC results as a function of the system Modulation Transfer Function (MTF). It will show that when making spatial resolution decisions (including speckle size) the resolution limiting component should be considered. A consequence of the loss of spatial resolution is that the DIC uncertainties will be increased. This is demonstrated using both synthetic and experimental images with varying resolution. The loss of image resolution and DIC accuracy can be compensated for by increasing the subset size, or better, by increasing the speckle size. The speckle-size and spatial resolution are now a function of the lens resolution rather than the more typical assumption of the pixel size. The paper will demonstrate the tradeoffs associated with limited lens resolution.

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Supercritical Carbon Dioxide (S-CO2) is an efficient and flexible working fluid for power production. Research to interface S-CO2 systems with nuclear, thermal solar, and fossil energy sources is currently underway. To proceed, we must address concerns regarding compatibility of materials, at high temperature, and compatibility between significantly different heat transfer fluids. Dry, pure S-CO2 is thought to be relatively inert [1], while the addition of ppm levels of water and oxygen result in formation of a protective chromia layer and iron oxide [2]. Thin oxides are favorable as diffusion barriers, and for their minimal impact on heat transfer. While S-CO2 is typically understood to be the secondary fluid, many varieties of primary fluids exist for nuclear applications. Molten salts, for use in the Molten Salt Reactor concept, are given as an example to contrast the materials requirements of primary and secondary fluids. Thin chromia layers are soluble in molten salt systems (nitrate, chloride, and fluoride based salts) [3-8], making materials selection for heat exchangers a precarious balancing act between high temperature oxidation (S-CO2) and metal dissolution (salt side of heat exchanger). Because concerns have been raised regarding component lifetimes, S-CO2 work has begun to characterize starting materials and to establish a baseline by analysis of 1) as-received stainless steel piping, and 2) piping exposed to S-CO2 under typical operating conditions with Sandia National Laboratories Brayton systems. A second issue discovered by SNL involves substantial erosion in the turbine blade and inlet nozzle. It is believed that this is caused by small particulates that originate from different materials around the loop that are entrained by the S-CO2 to the nozzle, where they impact the inlet nozzle vanes, causing erosion. We believe that, in some way, this is linked to the purity of the S-CO2, the corrosion contaminants, and the metal particulates that are present in the loop and its components.