Liquid hydrogen (LH2) used as a fuel onboard a heavy-duty vehicle can result in increased storage capacity and faster refueling relative to compressed gas. However, there are concerns about hydrogen losses from boil-off, potential safety issues, gaps in codes and standards for cryogenic hydrogen fuel, and technical challenges with LH2 systems for widespread transportation applications. A failure modes and effects analysis (FMEA), a safety codes and standards review, and a design review of the onboard liquid hydrogen system for a heavy-duty vehicle identified some of these potential safety issues and gaps in the codes and standards. The FMEA identified some medium and low risk failure points of the conceptual design, and the design review identified how carefully pressure relief needs to be considered for LH2 systems. In addition, a conceptual design for a LH2 refueling station was developed. Rough capital costs for the refueling station design were $\$1 million$ and the layout occupied approximately 13,000 ft2. These results can be used to inform future designs and analyses for LH2 heavy-duty vehicles.
The feasibility and component cost of hydrogen rail refueling infrastructure is examined. Example reference stations can inform future studies on components and systems specifically for hydrogen rail refueling facilities. All of the 5 designs considered assumed the bulk storage of liquid hydrogen on-site, from which either gaseous or liquid hydrogen would be dispensed. The first design was estimated to refuel 10 multiple unit trains per day, each train containing 260 kg of gaseous hydrogen at 350 bar on-board. The second base design targeted the refueling of 50 passenger locomotives, each with 400 kg of gaseous hydrogen on-board at 350 bar. Variations from this basic design were made to consider the effect of two different filling times, two different hydrogen compression methods, and two different station design approaches. For each design variation, components were sized, approximate costs were estimated for major components, and physical layouts were created. For both gaseous hydrogen-dispensing base designs, the design of direct-fill using a cryopump design was the lowest cost due to the high cost of the cascade storage system and gas compressor. The last three base designs all assumed that liquid hydrogen was dispensed into tender cars for freight locomotives that required 7,500 kg of liquid hydrogen, and the three different designs assumed that 5, 50, or 200 tender cars were refueled every day. The total component costs are very different for each design, because each design has a very different dispensing capacity. The total component cost for these three designs are driven by the cost of the liquid hydrogen tank; additionally, delivering that much liquid hydrogen to the refueling facility may not be practical. Many of the designs needed the use of multiple evaporators, compressors, and cryopumps operating in parallel to meet required flow rates. In the future, the components identified here can be improved and scaled-up to better fit the needs of heavy-duty refueling facilities. This study provides basic feasibility and first-order design guidance for hydrogen refueling facilities serving emerging rail applications.
Energy utilities are evaluating emerging energy technologies to reduce reliance on carbon as an energy carrier. Hydrogen has been identified as a potential substitute for carbon-based fuels that can be blended into other gaseous energy carriers, such as natural gas. However, hydrogen blending into natural gas has important implications on safety which need to be evaluated. Designers and installers of systems that utilize hydrogen gas blending into natural gas distribution systems need to adhere to local building codes and engage with the authority having jurisdiction (AHJ) for safety and permitting approvals. These codes and standards must be considered to understand where safety gaps might be apparent when injecting hydrogen into the natural gas infrastructure. This report generates a list of relevant codes and standards for hydrogen blending on existing, upgraded, or new pipelines. Additionally, a preliminary assessment was made to identify the codes and standards that need to be modified to enable this technology as well as potential gaps due to the unique nature and safety concerns of gaseous hydrogen.
Hydrogen can be used to reduce carbon emissions by blending into other gaseous energy carriers, such as natural gas. However, hydrogen blending into natural gas has important implications for safety which need to be evaluated. Hydrogen has different physical properties than natural gas, and these properties affect safety evaluations concerning a leak of the blended gas. The intent of this report is to begin to investigate the safety implications of blending hydrogen into the natural gas infrastructure with respect to a leak event from a pipeline. A literature review was conducted to identify existing data that will better inform future hazard and risk assessments for hydrogen/natural gas blends. Metrics with safety implications such as heat flux and dispersion behavior may be affected by the overall blend ratio of the mixture. Of the literature reviewed, there was no directly observed separation of the hydrogen from the natural gas or methane blend. No literature was identified that experimentally examined unconfined releases such as concentration fields or concentration at specific distances. Computational efforts have predicted concentration fields by modified versions of existing engineering models, but the validation of these models is limited by the unavailability of literature data. There are multiple literature sources that measured flame lengths and heat flux values, which are both relevant metrics to risk and hazard assessments. These data can be more directly compared to the outputs of existing engineering models for validation.
Several Department of Energy (DOE) facilities have materials stored in robust, welded, stainless - steel containers with presumed fire - induced pressure response behaviors. Lack of test data related to fire exposure requires conservative safety analysis assumptions for container response at these facilities. This conservatism can in turn result in the implementation of challenging operational restrictions with costly nuclear safety controls. To help address this issue for sites that store DOE 3013 stainless - steel containers, a series of ten tests were undertaken at Sandia National Laboratories. The goal of this test series was to obtain the response behavior for various configurations of DOE 3013 containers with various payload compositions when exposed to one of two ASTM fire conditions. Key parameters measured in the test series included identification of failure - specific characteristics such as pressure, temperature, and whether or not a vessel was breached during a test . Numerous failure - specific characteristics were identified from the ten tests. This report describes the implementation and execution of the test series performed to identify these failure - specific characteristics. Discussions on the test configurations, payload compositions, thermal insults, and experimental setups are presented. Test results in terms of pressurization and vessel breach (or no - breach) are presented along with corresponding discussions for each test.
The application of hydrogen as an energy carrier has been expanding into industrial and transportation sectors enabling sustainable energy resources and providing a zero-emission energy infrastructure. The hydrogen supply infrastructure includes processes from production and storage, to transportation and distribution, to end use. Each portion of the hydrogen supply infrastructure is regulated by international, federal, state, and local entities. Regulations are enforced by entities which provide guidance and updates as necessary. While energy sources such as natural gas are currently regulated via the Code of Federal Regulations and United States Code, there might be some ambiguity as to which regulations are applicable to hydrogen and where regulatory gaps may exist. This report contains an overview of the regulations that apply to hydrogen, and those that may indirectly cover hydrogen as an energy carrier participating in a sustainable zero emission global energy system. As part of this effort, the infrastructure of hydrogen systems and regulation enforcement entities are defined, and a visual map and reference table are developed. This regulatory map and table can be used to identify the boundaries of federal oversight for each component of the hydrogen supply value chain which includes production, storage, distribution, and use.
Several Department of Energy (DOE) facilities have nuclear or hazardous materials stored in robust, welded, stainless-steel containers with undetermined fire-induced pressure response behaviors. Lack of test data related to fire exposure requires conservative safety analysis assumptions for container response at these facilities. This conservatism can in turn result in the implementation of challenging operational restrictions with costly nuclear safety controls. To help address this issue for sites that store DOE 3013 stainless-steel containers, a series of five tests were undertaken at Sandia National Laboratories. The goal of this test series was to obtain the response behavior for various configurations of the DOE 3013 containers when exposed to various fire conditions. Key parameters measured in the test series included identification of failure-specific characteristics such as pressure, temperature, and leak/burst failure type. This paper describes the development and execution of the test series performed to identify these failure-specific characteristics. Work completed to define the test configurations, payload compositions, thermal insults, and experimental setups are discussed. Test results are presented along with corresponding discussions for each test.
Often in fire resistance testing of packaging vessels and other components, both the heat source temperature and the incident heat flux on a test specimen need to be measured and correlated. Standards such as ASTM E1529 require a specified temperature range from the heat source and a specified heat flux on the surface of the test specimen. There are other standards that have similar requirements. The geometry of the test environment and specimen may make heat flux measurements using traditional instruments (directional flame thermometers (DFTs) and water-cooled radiometers) difficult to implement. Orientation of the test specimen with respect to the thermal environment is also important to ensure that the heat flux on the surface of the test specimen is properly measured. Other important factors in the flux measurement include the thermal mass and surface emissivity of the test specimen. This paper describes the development of a cylindrical calorimeter using water-cooled wide-angle Schmidt-Bolter gauges to measure the incident heat flux for a vessel exposed to a radiant heat source. The calorimeter is designed to be modular to be modular with multiple configurations while meeting emissivity and thermal mass requirements via a variable thermal mass. The results of the incident heat flux and source temperature along with effective/apparent emissivity calculations are discussed.
Baird, Austin R.; Archibald, Erik J.; Marr, Kevin C.; Ezekoye, Ofodike A.
Lithium-ion battery technology is rapidly being adopted in transportation applications and energy storage industries. Safety concerns, in particular, fire and explosion hazards, are threatening widespread adoption. In some failure events, lithium-ion cells can undergo thermal runaway, which can result in the release of flammable gases that pose fire and explosion hazards for the compartment housing the cells. However, there is little available information characterizing the flammability properties of the gases released after cell thermal runaway. In this paper, analytical and modeling methods to estimate explosion characteristics, such as lower flammability limit, laminar flame speed, and maximum over-pressure are evaluated for use in quantifying the effect of cell chemistry, state-of-charge and other parameters on the overall explosion hazard potential for confined cells.