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YbH+ formation in an ytterbium ion trap

Hoang, Thai M.; Jau, Yuan-Yu J.; Overstreet, Richard; Schwindt, Peter S.

The trapped Yb+171 ion is a promising candidate for portable atomic clock applications. However, with buffer-gas cooled ytterbium ions, the ions can be pumped into a low-lying F7/22 state or form YbH+ molecules. These dark states reduce the fluorescence signal from the ions and can degrade the clock stability. In this work, we study the dynamics of the populations of the F7/22 state and YbH+ molecules under different operating conditions of our Yb+171 ion system. Our study indicates that F7/22-state ions can form YbH+ molecules through interactions with hydrogen gas. As observed previously, dissociation of YbH+ is observed at wavelengths around 369 nm. We also demonstrate YbH+ dissociation using 405 nm light. Moreover, we show that the population in the dark states can be limited by using a single repump laser at 935 nm. Our study provides insights into the molecular formation in a trapped ion system.