Publications

Water availability inside proposed Yucca mountain repository breached waste packages

Wang, Yifeng; Jove Colon, Carlos F.; Lord, Michael E.; Mattie, Patrick D.; MacKinnon, R.J.

We present a model to evaluate the water mass balance inside a breached waste package in Yucca Mountain (YM) repository environments. The amount of water as liquid or vapor that can accumulate inside or percolate through the package in the emplacement drift is modeled as a function of the temperature and relative humidity (RH) near the waste package, the dripping rate of water from seepage, the area of failure patches on the waste package, and the extent of waste degradation. The water activity inside the waste package is assumed to be determined by both matric and osmotic potentials in the porous waste degradation products that also includes hygroscopic salts. We implemented the model and conducted a set of Monte Carlo simulations to gain insight into the variability and uncertainty associated with model predictions. The model shows that water vapor diffusion can be as important as the advective seepage flow. In addition, chemical reactions during waste degradation can consume a significant fraction of water accumulated in the waste package.