Publications

Synthesis and unusual properties of the first 2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetraalkylporphyrin

Shelnutt, John A.; Shelnutt, John A.

The new perhalogenated porphyrin 2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetrakis(trifluoromethyl)porphinato-nickel(II) exhibits several striking features, including an extremely ruffled macrocycle with a very short Ni-N distance, an unusually red-shifted optical spectrum, and, surprisingly, hindered rotation of the meso-trifluoromethyl substituents ({Delta}G{sub 278}{sup +} = 47 kJ/mol).