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Stress corrosion cracking mechanism of cold spray coating on a galvanically similar substrate

Qu, Haozheng J.; Srinivasan, Jayendran; Zhao, Yangyang; Mao, Keyou S.; Taylor, Jason M.; Marino, Gabriella; Montoya, Timothy M.; Johnson, Kyle; Locke, Jenifer S.; Schaller, Rebecca S.; Schindelholz, Eric; Wharry, Janelle P.

The chloride-induced stress corrosion cracking (CISCC) mechanism of cold spray (CS) coating on a galvanically similar substrate is investigated. Arc welded 304L stainless steel (SS) specimens are loaded into four-point bend fixtures, cold sprayed with 304L SS, then immersed in boiling MgCl2. Interconnected porosity forms through crevice corrosion along CS splat boundaries, allowing corrosive species to penetrate through the CS layer. Nevertheless, the substrate is resistant to CISCC likely because of compressive stress introduced by peening during CS particle impacts. These findings underscore the importance of residual stress in the environmental degradation of CS coatings or repairs of engineering structures.