Publications

Real-time downhole measurement of ionic tracer concentration and pH in geothermal reservoirs

Hess, Ryan F.; Boyle, Timothy J.; Limmer, Steven J.; Yelton, William G.; Bingham, Samuel; Stillman, Greg; Cieslewski, Grzegorz C.

Chemical tracers are commonly used to characterize the fracture network and determine the connectivity between the injection and production wells. Currently, most tracer experiments involve injecting the tracer at the injection well, manually collecting liquid samples at the wellhead of the production well, and sending the samples off for laboratory analysis. While this method provides accurate tracer concentration data at very low levels of detection, it does not provide information regarding the depth of the fractures which were conducting the tracer between wellbores. Sandia is developing a high-temperature electrochemical sensor capable of measuring ionic tracer concentration and pH downhole on a wireline tool. The goal of this effort is to collect real-time pH and ionic tracer concentration data at temperatures up to 225 °C and pressures up to 3000 psi. In this paper, a prototype electrochemical sensor and the initial data obtained will be presented detailing the measurement of iodide tracer concentrations at high temperature and pressure in a newly developed laboratory scale autoclave. Efforts to expand this tool to measure lithium, cesium, and fluoride ion tracers will be discussed as well.