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Reactive ion-assisted deposition of e-beam evaporated titanium for high refractive index TiO2layers and laser damage resistant, broad bandwidth, high-reflection coatings

Bellum, John C.; Field, Ella S.; Kletecka, Damon E.; Long, Finis W.

High-reflection coatings with broad bandwidth can be achieved by pairing a low refractive index material, such as SiO2, with a high refractive index material, such as TiO2. To achieve high refractive index, low absorption TiO2films, we optimized the reactive, ion-assisted deposition process (O2levels, deposition rate, and ion beam settings) using e-beam evaporated Ti. TiO2high-index layers were then paired with SiO2low-index layers in a quarter-wave-type coating to achieve a broader high-reflection bandwidth compared to the same coating composed of HfO2/SiO2layer pairs. However, the improved bandwidth exhibited by the TiO2/SiO2coating is associated with lower laser damage threshold. To improve the laser damage resistance of the TiO2/SiO2coating, we also created four coatings where HfO2replaced some of the outer TiO2layers. We present the laser damage results of these coatings to understand the trade-offs between good laser damage resistance and high-reflection bandwidth using TiO2and HfO2.