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Numerical study of pyrolysis and combustion of a carbon fiber-epoxy composite

Koo, Heeseok K.; Brown, Alexander B.; Voskuilen, Tyler V.; Pierce, Flint P.

With growing use of carbon fiber-epoxy in transportation systems, it is important to understand fire reaction properties of the composite to ensure passenger safety. Recently, a micro-scale pyrolysis study and macro-scale fire tests were performed using carbon fiber-epoxy at Sandia National Laboratories. Current work focuses on numerical modeling of the material conversion, pyrolysis, and gas-phase combustion that replicate the experiments. Large-eddy simulations (LES) and eddy-dissipation concept (EDC) approach are incorporated in the gas phase along with multiple relevant reaction model methods in the solid phase. The numerical methods that use multi-step pyrolysis rate expressions are validated by thermogravimetric analysis (TGA) results. The pyrolyzed fuel components participate in gas-phase combustion using a turbulent combustion model. The multi-phase combustion capability was further assessed using two cases: a single particle reaction and a solid panel exposed to strong radiant heat. The panel fire test indicates that the model accurately reproduces panel temperature profile while a weaker oxidation is predicted.