Publications

Mechanical characterization of low modulus polymer-modified calcium-silicate-hydrate (C–S–H) binder

Starr, J.; Soliman, E.M.; Matteo, Edward N.; Dewers, Thomas D.; Stormont, J.C.; Reda Taha, M.M.

Calcium-silicate-hydrate (C–S–H) represents a key microstructural phase that governs the mechanical properties of concrete at a large scale. Defects in the C–S–H phase are also responsible for the poor ductility and low tensile strength of concrete. Manipulating the microstructure of C–S–H can lead to new cementitious materials with improved structural performance. This paper presents an experimental investigation aiming to characterize a new synthetic polymer-modified synthetic calcium-silicate-hydrate (C–S–H)/styrene-butadiene rubber (SBR) binder. The new C–S–H/SBR binder is produced by calcining calcium carbonate and mixing this with fumed silica (SiO2), deionized water and SBR. Mechanical, physical, chemical and microstructural characterization was conducted to measure the properties of new hardened C–S–H binder. Results from the experimental investigation demonstrate the ability to engineer a new C–S–H binder with low elastic modulus and improved toughness and bond strength by controlling the SBR content and method of C–S–H synthesis. The new binder suggests the possible development of a new family of low-modulus silica-polymer binders that might fit many engineering applications such as cementing oil and gas wells.