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Laboratory gas migration experiments through intact and fractured rock

Broome, Scott T.; Feldman, Joshua D.; Cashion, Avery T.

Presented herein are laboratory gas migration experiments conducted on samples of tuff with varying lithologies mounted within a triaxial core holder. A pressurized gas mixture standard comprised of known concentrations of argon (Ar), xenon (Xe), nitrogen (N2) and sulfur hexafluoride (SF6used as a tracer) was used based on previous field gas migration studies. The gas mix is applied at known pressure to the upstream side of the samples to induce flow through the pore spaces and/or across fracture surfaces and the gases are detected in real-time on the downstream side using a quadrupole mass spectrometer (QMS). Downstream detection under vacuum is possible by precise metering of the gas mixture through a leak valve with active feedback control. Arrival times and time-variant concentrations of the applied gases downstream are collected for comparison between samples. We intend to determine transport properties of noble gases and SF6, and hypothesize that transport properties vary due to solubility and water content. The parameters derived from this work will provide valuable insight into the three-dimensional structure of damage zones, including fracture networks, the production of temporally variable signatures, and the methods to best detect underground nuclear explosion signatures.