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Ionic liquid flow battery materials and prototyping

Anderson, Travis M.; Pratt, Harry P.

SNL has developed a series of ionic-liquid electrolytes with accompanying non- Aqueous compatible membranes and flow cell designs for improved energy density redox flow batteries targeted to support increasing demands for stationary energy storage. The new electrolytes yield a higher energy density by chemically incorporating an electro- Active transition metal element into the solvent's molecular formula. Although ionic liquids have higher viscosities than conventional non- Aqueous electrolytes, they are promising for higher energy densities due to higher metal concentrations and wider voltage windows. We have addressed high viscosity by developing new materials through careful ligand and anion selection. We have also developed tunable membranes for non- Aqueous compatibility and rapid laboratory-scale prototyping to quickly screen materials and cell designs. We are projecting a four-fold improvement in energy density over the next two years.