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Hydrogen-Assisted fracture of low nickel content 304 and 316l austenitic stainless steels

Marchi, C.S.; Yang, Nancy Y.; Headley, T.J.; Michael, Joseph R.

There has been significant debate in the literature about the role of strain-induced martensite in hydrogen-Assisted fracture of metastable austenitic stainless steels. It is clear that α'-martensite is not necessary for hydrogen-Assisted fracture since hydrogen affects the tensile ductility and fracture properties of stable austenitic stainless steels. Martensite, however, is believed to facilitate hydrogen transport in austenitic stainless steel and numerous studies propose that martensite contributes to fracture. Yet conclusive evidence that strain-induced α'-martensite plays an important mechanistic role on fracture processes in the presence of hydrogen has not been clearly articulated in the literature. In this study, we report microstructural evidence suggesting that α'-martensite does not play a primary role in hydrogen-Assisted fracture during tensile testing of metastable austenitic stainless steel. This microstructural evidence also suggests that thermal twin boundaries are susceptible sites for hydrogen-Assisted fracture.