Publications

High performance reduction/oxidation metal oxides for thermochemical energy storage (PROMOTES)

Miller, James E.; Ambrosini, Andrea A.; Babiniec, Sean M.; Coker, Eric N.; Ho, Clifford K.; Al-Ansary, Hany; Jeter, Sheldon M.; Loutzenhiser, Peter G.; Johnson, Nathan G.; Stechel, Ellen B.

Thermochemical energy storage (TCES) offers the potential for greatly increased storage density relative to sensible-only energy storage. Moreover, heat may be stored indefinitely in the form of chemical bonds via TCES, accessed upon demand, and converted to heat at temperatures significantly higher than current solar thermal electricity production technology and is therefore well-suited to more efficient high-temperature power cycles. The PROMOTES effort seeks to advance both materials and systems for TCES through the development and demonstration of an innovative storage approach for solarized Air-Brayton power cycles and that is based on newly-developed redox-active metal oxides that are mixed ionic-electronic conductors (MIEC). In this paper we summarize the system concept and review our work to date towards developing materials and individual components.