Publications

Direct Observations of a Dynamically Driven Phase Transition with in situ X-Ray Diffraction in a Simple Ionic Crystal

Kalita, Patricia K.; Specht, Paul E.; Root, Seth R.; Sinclair, Nicolas S.; Schuman, Adam S.; White, Melanie W.; Cornelius, Andrew, L.; Smith, Jesse S.; Sinogeikin, Stanislav S.

Here, we report real-time observations of a phase transition in the ionic solid CaF₂, a model AB₂ structure in high-pressure physics. Synchrotron x-ray diffraction coupled with dynamic loading to 27.7 GPa, and separately with static compression, follows, in situ, the fluorite to cotunnite structural phase transition, both on nanosecond and on minute time scales. Using Rietveld refinement techniques, we examine the kinetics and hysteresis of the transition. Our results give insight into the kinetic time scale of the fluorite-cotunnite phase transition under shock compression, which is relevant to a number of isomorphic compounds.