Publications

Crystal and Electronic Structures of A₂NaIO₆ Periodate Double Perovskites (A = Sr, Ca, Ba): Candidate Wasteforms for I-129 Immobilization

O?Sullivan, Sarah E.; Montoya, Eduardo M.; Sun, Shi K.; Vasiliauskas, Jonathan G.; Kirk, Cameron K.; Dixon Wilkins, Malin C.; Weck, Philippe F.; Kim, Eunja K.; Knight, Kevin S.; Hyatt, Neil C.

The synthesis, structure, and thermal stability of the periodate double perovskites A₂NaIO₆ (A= Ba, Sr, Ca) were investigated in the context of potential application for the immobilization of radioiodine. A combination of X-ray diffraction and neutron diffraction, Raman spectroscopy, and DFT simulations were applied to determine accurate crystal structures of these compounds and understand their relative stability. The compounds were found to exhibit rock-salt ordering of Na and I on the perovskite B-site; Ba₂NaIO₆ was found to adopt the Fm-3m aristotype structure, whereas Sr₂NaIO₆ and Ca₂NaIO₆ adopt the P2₁/n hettotype structure, characterized by cooperative octahedral tilting. DFT simulations determined the Fm-3m and P2₁/n structures of Ba₂NaIO₆ to be energetically degenerate at room temperature, whereas diffraction and spectroscopy data evidence only the presence of the Fm-3m phase at room temperature, which may imply an incipient phase transition for this compound. The periodate double perovskites were found to exhibit remarkable thermal stability, with Ba₂NaIO₆ only decomposing above 1050 °C in air, which is apparently the highest recorded decomposition temperature so far recorded for any iodine bearing compound. As such, these compounds offer some potential for application in the immobilization of iodine-129, from nuclear fuel reprocessing, with an iodine incorporation rate of 25–40 wt%. The synthesis of these compounds, elaborated here, is also compatible with both current conventional and future advanced processes for iodine recovery from the dissolver off-gas.