Publications

Alloy depletion and martensite formation during glass-to-metal joining of austenitic stainless steels

Susan, D.F.; Perricone, M.J.; Robino, C.V.; Michael, Joseph R.; McKenzie, Bonnie B.; Rodriguez, Marko A.

Pre-oxidized and glass-to-metal (GtM) sealed austenitic stainless steels were found to display a ferritic layer near the metal/oxide interface, as determined by electron backscatter diffraction (EBSD). Electron probe microanalysis (EPMA) showed that this layer was depleted in alloying elements due to the oxidation and sealing process. Characterization of the morphology suggested that it formed through the martensite transformation mechanism. Moreover, this observed layer was correlated to the composition gradient through published empirical relationships for martensite-start (Ms) temperatures. Due to Cr, Mn, and Si depletion during pre-oxidation and glass sealing, Ms temperatures near room temperature are possible in this surface region. Further support for a martensitic transformation was provided by thermochemical modeling. Possible detrimental ramifications of bulk composition, surface depletion, and phase transformations on GtM sealing are discussed. Copyright © 2007 MS&T'07®.