828/Z

Composition

  • 100 pbw digylcidyl ether of bisphenol A (Epon 828)
  • 20 pbw aromatic amine curing agent Ancamine Z
  • Cured 24 hours at 93C
  • Tg of fully cured 828/Z is ~170C.
  • For isothermal cure, reaction quenches when Tg exceeds the cure temperature.
  • Tg can only achieve about 25C above the cure temperature, so cure at 93C yields Tg of ~ 118C.
  • Determination of fully cure Tg required higher temperature post cure.
  • Since 93C cure is incomplete, excursions above 93C for characterization will result in continued cure.
  • Therefore, a master curve cannot be obtained and characterization of G’, CTE, and Cp above Tg of “as-cured” material is not valid.