828/DEA: Gelation Reaction Kinetics

(i.e., after pre-reaction)

Isothermal cure measured with a TA Instruments Q2000 DSC.

Since the reaction mechanism changes, the rate equation is complicated (epoxy-alcohol at lower temps and epoxy homopolymerization at higher temps).

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65C75C85C95C
Time (s) Time (s) Time (s) Time (s)
Extent Extent Extent Extent

heat of reaction ~ 260 J/g

extent of reaction at the gel point ~ 2/3