Laboratory Publications

2022

  • Matthew S. Christian, Keith J. Fritzsching, Jacob A. Harvey, Dorina F. Sava Gallis, Tina M. Nenoff, and Jessica M. Rimsza, “Dramatic Enhancement of Rare-Earth Metal–Organic Framework Stability Via Metal Cluster Fluorination”, J.A.C.S. Au (2022) https://doi.org/10.1021/jacsau.2c00259
  • Jessica N. Domrzalski, Tyler E. Stevens, Renee M. Van Ginhoven, Keith J. Fritzsching, Brennan J. Walder, Emily M. Johnson, Riley E. Lewis, Erika C. Vreeland, Charles J. Pearce, David A. Vargas, Eric N. Coker, Estevan J. Martinez, John K. Grey and Todd C. Monson, “Surface Functionalized Barium Titanate Nanoparticles: A Combined Experimental and Computational Study”, E.C.S J. Solid State Sci. Tech. 11(6) 063006 (2022) https://doi.org/10.1149/2162-8777/ac6f7d
  • Brennan J. Walder, Noah B. Schorr, Lyle B. Brunke, Michael P. Siegal, Todd M. Alam, Keith J. Fritzsching, and Timothy N. Lambert, “Composites of (C4F)n and (CF)n Synthesized by Uncatalyzed Fluorination of Graphite”, Solids 3(2) 237-257 (2022) https://doi.org/10.3390/solids3020017

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Dr. Todd M. Alam retired from Sandia National Laboratories in 2021. He led or was part of the vast majority of the remaining publication on this list.

2021

  • Jessica M. Rimsza, Brennan J. Walder, and Todd M. Alam, “Influence of Polymorphs and Local Defect Structures on NMR Parameters of Graphite Fluorides”, J. Phys. Chem. C 125(4) 2699-2712 (2021) https://doi.org/10.1021/acs.jpcc.0c09957
  • Brennan J. Walder and Todd M. Alam, “Modes of Disorder in Poly(carbon monofluoride)”, J. Am. Chem. Soc., 143(30), 11714-11733 (2021) https://doi.org/10.1021/jacs.1c05234      
  • Cocoro A. Nagasaka, Karoly Kozma, Kieran G. Brunson, Chris J. Russo, Todd M. Alam, and MayNyman, “Cs absorption capacity and selectivity of crystalline and amorphous Hf and Zr phosphates”, Polyhedron, 202, 115199 (2021) https://doi.org/10.1016/j.poly.2021.115199
  • J. P. Allers, F. H. Garzon, T. M. Alam, “Artificial Neural Network Prediction of Self-Diffusion in Pure Compounds over Multiple Phase Regimes”, Phys. Chem. Chem. Phys. 23, 4615 – 4623 (2021). 2021 HOT PCCP article https://doi.org/10.1039/D0CP06693A
  • Rimsza, J. M.; Walder, B. J.; Alam, T. M. Influence of Polymorphs and Local Defect Structures on NMR Parameters of Graphite Fluorides. J. Phys. Chem. C, 125, 2699-2712 (2021). https://doi.org/10.1021/acs.jpcc.0c09957 

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2020

  • Calen J. Leverant, Jacob A. Harvey, Todd M. Alam, “Machine Learning-Based Upscaling of Finite-Size Molecular Dynamics Diffusion Simulations for Binary Fluids.” The Journal of Physical Chemistry Letters, 11(24), 10375-10381 (2020), https://doi.org/10.1021/acs.jpclett.0c03108
  • Wenxin Fu, Todd M. Alam, Jiachen Li, Jacqueline Bustamante, Thanh Lien, Ralph W. Adams, Simon J. Teat, Benjamin J. Stokes, Weitao Yang, Yi Liu, and Jennifer Q. Lu, “Arene Substitution Design for Controlled Conformational Changes of Dibenzocycloocta-1,5-dienes”, J. Am. Chem. Soc.,  142(39), 16651-16660 (2020), DOI: 10.1021/jacs.0c06579
  • J. K. Elinburg, A. S. Hyre, J. McNeely, T. M. Alam, S. Klenner, R. Pöttgen, A. L. Rheingold, L. H. Doerrer, “Formation of Monomeric Sn(ii) and Sn(iv) Perfluoropinacolate Complexes and Their Characterization by 119Sn Mössbauer and 119Sn NMR Spectroscopies. Dalton Transactions, 49, 13773-13785 (2020). https://doi.org/10.1039/D0DT02837A
  • Brad H. Jones, Todd M. Alam, Sangwoo Lee, Mathew C. Celina, Joshua P. Allers, Sungmin Park, Liwen Chen, Estevan J. Martinez, Jaclynn L. Unangst, ”Curing behavior, chain dynamics, and microstructure of high Tg thiol-Acrylate networks with systematically varied network heterogeneity”, Polymer, 205, 122783, (2020), https://doi.org/10.1016/j.polymer.2020.122783.
  • R. J. McCarty, N. Ronghe, M. Woo, T. M. Alam, “Blind Source Separation for NMR Spectra with Negative Intensity.” Preprints, 2020020113 (2020) doi: 10.20944/preprints202002.0113.v1
  • Eric G. Sorte, Jessica M. Rimsza, and Todd M. Alam, “Computational and Experimental 1H-NMR Study of Hydrated Mg-Based Minerals”, Molecules (2020) 25(4), 933. https://doi.org/10.3390/molecules25040933
  • Brennan J. Walder, Todd M. Alam, “Quantification of Uncoupled Spin Domains in Spin-Abundant Disordered Solids.” Int. J. Mol. Sci. (2020), 21, 3938. https://doi.org/10.3390/ijms21113938
  • Joshua P. Allers, Jacob A. Harvey, Fernando H. Garzon, Todd M. Alam, “Machine Learning Prediction of Self-Diffusion in Lennard-Jones Fluids”, Journal of Chemical Physics (2020), 153, 034102. https://aip.scitation.org/doi/10.1063/5.0011512
  • Todd M. Alam, Joshua P. Allers, Brad H. Jones, “Heterogeneous Polymer Dynamics Explored Using Static 1H NMR Spectra”, Int. J. Mol. Sci. 2020, 21, 5176. https://doi.org/10.3390/ijms21155176

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2019

  • Todd M. Alam and Brad H. Jones, “Investigating Chain Dynamics in Highly Crosslinked Polymers using Solid‐State 1H NMR Spectroscopy”, Journal of Polymer Science, Part B Polymer Physics, Early View (2019). https://onlinelibrary.wiley.com/doi/abs/10.1002/polb.24869
  • Todd M. Alam, “Chapter 4: High Resolution Magic Angle Spinning (HRMAS) Pulse Field Gradient (PFG) NMR Diffusometry Studies of Swollen Polymers”, in NMR Methods for Characterization of Synthetic and Natural Polymers”, Ed. R. Zhang, T. Miyoshi and P. Sun, pg. 63-79 (2019). https://pubs.rsc.org/en/content/ebook/978-1-78801-400-7
  • Eric G. Sorte, Amalie L. Frischknecht, Todd M. Alam, “NMR spin diffusion measurements in disordered polymers: Insights and limitations.” Physical Review Materials, 3 (4), 045602 (2019). 10.1103/PhysRevMaterials.3.045602
  • Eric G. Sorte, Benjamin A. Paren, Christina G. Rodriguez, Cy Fujimoto, Cassandria Poirier, Lauren J. Abbott, Nathaniel A. Lynd, Karen I. Winey, Amalie L. Frischknecht, and Todd M. Alam, “Impact of Hydration and Sulfonation on the Morphology and Ionic Conductivity of Sulfonated Poly(phenylene) Proton Exchange Membranes”, Macromolecules 52, 857-876 (2019). DOI: 10.1021/acs.macromol.8b02013
  • Jessica M. Rimsza, Eric G. Sorte, and Todd M. Alam, “Hydration and Hydroxylation of MgO in Solution: NMR Identification of Proton-Containing Intermediate Phases” ACS Omega 4(1), 1033-1044 (2019) DOI: 10.1021/acsomega.8b02705
  • Boyle, T. J.; Guerrero, F.; Alam, T. M.; Dunnigan, K. A.; Sears, J. M.; Wheeler, D. R., “Trapped Intermediate of a Meerwein–Pondorf–Verley Reduction of Hydroxy Benzaldehyde to a Dialkoxide by Titanium Alkoxides.” Inorganic Chemistry (2019) 59, 880-890. https://pubs.acs.org/doi/abs/10.1021/acs.inorgchem.9b03134

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 2018

  • Eric G. Sorte, Lauren J. Abbott, Amalie L. Frischknecht, Mark Wilson, and Todd M. Alam, “Hydrophilic Domain Structure in Polymer Exchange Membranes: Simulations of NMR Spin Diffusion Experiments to Address Ability for Model Discrimination”, J. Polymer Science Part B: Polymer Physics, 56, 62-78 (2018). DOI:10.1002/polb.24439 
  • Timothy J. Boyle, Diana Perales, Jessica M. Rimsza, Todd M. Alam, Daniel M. Boye, Jeremiah M. Sears, Jeffery A. Greathouse and  Richard A. Kemp, “Synthesis and Characterization of Thallium–Salen Derivatives for use as Underground Fluid Flow Tracers”, Dalton Transactions, 47, 4162-4174 (2018) DOI: 10.1039/C7DT04121G  
  • Todd M. Alam, “Computational Study of Microhydration in Sulfonated Diels–Alder Poly(phenylene) Polymers”, J. Phys. Chem. A, 122, 3927-3938 (2018) DOI: 10.1021/acs.jpca.8b01354 
  • Jing Xie, Harrison A. Neal, Jennifer Szymanowski, Peter C. Burns, Todd M. Alam, May Nyman, and Laura Gagliardi, “Resolving Confined 7Li Dynamics of Uranyl Peroxide Capsule U24”, Inorganic Chemistry, 57, 5514-5525 (2018) DOI: 10.1021/acs.inorgchem.8b00474
  • M. S. Kent, J. Zeng, N. Rader, I. C. Avina, C. T. Simoes, C. K. Brenden, M. L. Busse, J. D. Watt, N. H. Giron, T. M. Alam, M. D. Allendorf, B. Simmons, N. S. Bell, K. L. Sale, K. L., “Efficient Conversion of Lignin into a Water-Soluble Polymer by a Chelator-Mediated Fenton Reaction: Optimization of H2O2 use and Performance as a Dispersant”, Green Chemistry, 20, 3024-3037 (2018) .doi: 10.1039/C7GC03459H 
  • E. G. Sorte, N. A. Banek, M. J. Wagner, T. M. Alam, and Y. J. Tong, Y. J. “In Situ Stripline Electrochemical NMR for Batteries”, ChemElectroChem., 16 35-36 (2018). doi:10.1002/celc.201800434
  •  Kyoungtae Kim, Shahab Kashani Rahimi, Todd M. Alam, Eric G. Sorte, and Joshua U. Otaigbe “Unexpected effects of inorganic phosphate glass on crystallization and thermo-rheological behavior of polyethylene terephthalate “, Polymer 154 135-147 (2018)       https://doi.org/10.1016/j.polymer.2018.08.066
  • Kyoungtae Kim, Todd M. Alam, Joseph D. Lichtenhan, Joshua U. Otaigbe, “Synthesis and characterization of novel phosphate glass matrix nanocomposites containing polyhedral oligomeric silsesquioxane with improved properties”. J. Non-Crystalline Solids, 463, 189-202 (2018). http://dx.doi.org/10.1016/j.jnoncrysol.2017.03.007
  • Kyoungtae Kim, William L.Jarrett, Todd M.Alam, Joshua U. Otaigbe, “Phosphate Glass Matrix Composites Incorporating Trisilanol Phenyl Polyhedral Oligomeric Silsesquioxane Prepared by Viscous Flow Sintering Method with Enhanced Benefits”, J. Non-Crystalline Solids, 503-504, 323-333 (2018). https://doi.org/10.1016/j.jnoncrysol.2018.10.018

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2017

  • Frederick G. Baddour, Ariel S. Hyre, Jesse L. Guillet, David Pascual, José Maria Lopez-de-Luzuriaga, Todd M. Alam, Jeffrey W. Bacon, and Linda H. Doerrer, “Pt–Mg, Pt–Ca, and Pt–Zn Lantern Complexes and Metal-Only Donor–Acceptor Interactions”, Inorganic Chemistry, 56(1), 452-469 (2017), DOI: 10.1021/acs.inorgchem.6b02372
  • Kyoungtae Kim, Todd M. Alam, Joseph D. Lichtenhan, Joshua U. Otaigbe, “Synthesis and Characterization of Novel Phosphate Glass Matrix Nanocomposites Containing Polyhedral Oligomeric Silsesquioxane with Improved Properties”, J. Non-Crystalline Solids, 463, 189-202 (2017). http://dx.doi.org/10.1016/j.jnoncrysol.2017.03.007
  • Brad H. Jones, David R. Wheeler, Hayden T. Black, Mark E. Stavig, Patricia S. Sawyer, Nicholas H. Giron, Mathias C. Celina, Timothy N. Lambert, and Todd M. Alam, “Stress Relaxation in Epoxy Thermosets via a Ferrocene-Based Amine Curing Agent”, Macromolecules, 50(13), 5014-5024 (2017) DOI: 10.1021/acs.macromol.7b00501
  • Eric G. Sorte and Todd M. Alam TM, “1H-19F REDOR-Filtered NMR Spin Diffusion Measurements of Domain Size in Heterogeneous Polymers” Magn. Reson. Chem., 1–9 (2017). https://doi.org/10.1002/mrc.4623
  • Travis A. Olds, Mateusz Dembowski, Xiaoping Wang, Christina Hoffman, Todd M. Alam, Sarah Hickam, Kristi L. Pellegrini, Junhong He, and Peter C. Burns, “Single-Crystal Time-of-Flight Neutron Diffraction and Magic-Angle-Spinning NMR Spectroscopy Resolve the Structure and 1H and 7Li Dynamics of the Uranyl Peroxide Nanocluster U60”, Inorganic Chemistry, 56(16), 9676-9683 (2017) DOI: 10.1021/acs.inorgchem.7b01174
  • Muge Acik, Todd M. Alam, Fangmin Guo, Yang Ren, Byeongdu Lee, Richard A. Rosenberg, J. F. Mitchell, In Kee Park, Geunsik Lee, Seth B. Darling “Substitutional Growth of Methylammonium Lead Iodide Perovskites in Alcohols”, Advanced Energy Materials, 1701726 (2017) DOI:10.1002/aenm.201701726

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2016

  • Todd M. Alam, Zuolei Liao, May Nyman and Jonathan Yates, “Insight into Hydrogen Bonding of Uranyl Hydroxide Layers and Capsules by Use of 1H Magic-Angle Spinning NMR Spectroscopy”, J. Phys. Chem. C, 120(19), 10675-10685 (2016) DOI: 10.1021/acs.jpcc.6b02692
  • Todd M. Alam and Thomas M. Osborn Popp, “In-Pore Exchange and Diffusion of Carbonate Solvent Mixture in Nanoporous Carbon” Chem. Phys. Lett., 658, 51-57 (2016). doi:10.1016/j.cplett.2016.06.014
  • Todd M. Alam, Mark K. Kinnan,Brendan W. Wilson, and David R. Wheeler, “Sub-Equimolar Hydrolysis and Condensation of Organophosphates”, Chemistry Select, 1, 2698-2705 (2016). DOI: http://onlinelibrary.wiley.com/doi/10.1002/slct.201600498/abstract
  • Timothy J. Boyle, Jeremiah M. Sears, Michael L. Neville, Todd M. Alam, Victor G, Young, “Structural Properties of the Acidification Products of Scandium Hydroxy Chloride Hydrate”, Inorganic Chemistry, 54(24), 11831-11841 (2016), DOI: 10.1021/acs.inorgchem.5b02030
  • Maryam K. Mardke, Baiyu Huang, Calvin H. Bartholomev, Todd M. Alam, Brian F. Woodfield, “Synthesis and Characterization of Silica Doped Alumina Catalyst Support with Superior Thermal Stability and Unique Pore Properties”, Journal Porous Materials, 23(2), 475-487 (2016).DOI: 10.1007/s10934-015-0101-z
  • Timothy J. Boyle, Michael L. Neville, Jeremiah M. Sears, Roger E. Cramer, Mark A. Rodriguez, Todd M. Alam, Samuel P. Bingham, “Synthesis, X-​ray Structures, and Characterization of Hexafluoro-​iso-​propoxide Group 3 and Lanthanide Precursors”, Polyhedron, 118, 52-60 (2016). dx.doi.org/10.1016/j.poly.2016.07.030

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2010 – 2015

  • Catherine FM Clewett, Todd M Alam, Eric S Osantowski and Michael J Pullin, “Structural Characterization of Humic Materials Using 13C Nuclear Magnetic Resonance Techniques: A Comparison of Solution and Solid-State Methods”, J. Environ. Anal. Chem., 2, 121 (2015). doi: 10.4172/JREAC.1000121
  • Todd M. Alam, C. J. Pearce, “Infrared Signature of Micro-Hydration in the Organophosphate Sarin: an Ab Initio Study”, Journal Molecular Modeling, 21(7), 1-8 (2015). DOI: 10.1007/s00894-015-2732-z
  • Todd M. Alam and Nelson Bell and Jill Wheeler and Erik D. Spoerke and Randall T. Cygan and David Ingersoll, “Exploring the Role of Phosphate Structural Distortions on the Sodium Jump Dynamics in NASICON Phases”, MRS Online Proceedings, 1773 (2015) mrss15-2126591,DOI: http://dx.doi.org/10.1557/opl.2015.522
  • Timothy J. Boyle, Michael L. Neville, Daniel T. Yonemoto, Todd M. Alam, Lily Jan, “Coordination Chemistry of 2,​6-​Dimethanol Pyridine with Early Transition Metal Alkoxide Compounds”, J. Coordination Chemistry, 68(9), 1616-1632 (2015). DOI:10.1080/00958972.2015.1028382
  • Brad H. Jones, David R. Wheeler, Jill S. Wheeler, Lance L. Miller, Todd M. Alam, and Erik D. Spoerke, “Isomer-Sensitive Deboronation in Reductive Aminations of Aryl Boronic Acids”, Tetrahedron Letters, 56, 5731-5734 (2015). doi:10.1016/j.tetlet.2015.09.006
  • Todd M. Alam and Charels J. Pearce, “Impact of Graphene Incorporation on the Orientational Order of Graphene/Liquid Crystal Composites”, Chem. Phys. Lett., 592, 7-13 (2014). http://dx.doi.org/10.1016/j.cplett.2013.11.044Todd M. Alam and Michael R. Hibbs, “Characterization of Heterogeneous Solvent Diffusion Environments in Anion Exchange Membranes”, Macromolecules, 47, 1073-1084 (2014). http://dx.doi.org/10.1021/ma402528v
  • Kamyar Keyvanloo, Maryam Khosravi Mardkhe, Todd M. Alam, Calvin H. Bartholomew, Brian F. Woodfield, and William C. Hecker, “Supported Iron Fischer–Tropsch Catalyst: Superior Activity and Stability Using a Thermally Stable Silica-Doped Alumina Support”, ACS Catalysis, 4, 1071-1077 (2014). http://dx.doi.org/10.1021/cs401242d
  • Rebecca E. Olsen, Todd M. Alam, Calvin H. Bartholomew, David B. Enfield, Jacob Schliesser, Brian F. Woodfield, “Structure Analysis of Al-Modified TiO2 Nano Catalyst Supports”, J. Phys. Chem. C, 118(17), 9176-9186 (2014). http://dx.doi.org/10.1021/jp411953d
  • Todd M. Alam, Zuolei Liao, Lev N. Zacharov, May Nyman, “Solid-State Dynamics of Uranyl Polyoxometalates”, Chemistry, A. Eur. J., 20(27), 8302-8307 (2014). http://dx.doi.org/10.1002/chem.201402351
  • Maryam Khosravi Mardkhe, Kamyar Keyvanloo, Calvin H. Bartholomew, William C. Hecker, Todd M. Alam, Brian F. Woodfield, “Acid Site Properties of Thermally Stable, Silica-Doped Alumina as a Function of Silica/Alumina Ratio and Calcination Temperature”, Applied Catalysis A: General, 482, 16-23 (2014). http://dx.doi.org/10.1016/j.apcata.2014.05.011
  • Todd M. Alam, Kimberly K. Childress, Kevin Pastoor, Charles V. Rice, “Characterization of Free, Restricted and Entrapped Water Environments in Poly(N-Isopropyl Acrylamide) Hydrogels via 1H HRMAS PFG NMR Spectroscopy”, J. Polymer Science: Polymer Physics, 52, 1521-1527 (2014) http://dx.doi.org/10.1002/polb.23591
  • Todd M. Alam, Daniel R. Dreyer, Christopher W. Bielawski, and Rodney S. Ruoff, “Combined Measurement of Translational and Rotational Diffusion in Quaternary Acyclic Ammonium and Cyclic Pyrrolidinium Ionic Liquids”, J. Phys. Chem. B, 117, 1967-1977 (2013). http://dx.doi.org/10.1021/jp3111953
  • Timothy J. Boyle, Andrew T. Velazquez, Daniel T. Yonemoto, Todd M. Alam, Curtis Moore, Arnold L. Rheingold, “Synthesis and Characterization of a Family of Solvated Sodium Aryloxide Compounds”, Inorganica Chimia Acta, 405, 374-386 (2013).       http://dx.doi.org/10.1016/j.ica.2013.06.015
  • Todd M. Alam, “Ab Initio Calculations of Possible γ-Gauche Effects in the 13C-NMR for Methine and Carbonyl Carbons in Precise Polyethylene Acrylic Copolymers”, Molecules, 18(8), (2013)9010-9020 http://dx.doi.org/10.3390/molecules18089010
  • C. Francisco Buitrago, Janelle E. Jenkins, Kathleen L. Opper, Brian S. Aitken, Kenneth B. Wagener, Todd M. Alam, and Karen I. Winey, “Room Temperature Morphologies of Precise Acid- and Ion-Containing Polyethylenes”, Macromolecules, 46(22), 9003-9012 (2013). http:/dx/doi.org/10.1021/ma4013169
  • C. Francisco Buitrago, Todd M. Alam, Kathleen L. Opper, Brian S. Aitken, Kenneth B. Wagener, and Karen I. Winey, “Morphological Trends in Precise Acid- and Ion-Containing Polyethylenes at Elevated Temperature”, Macromolecules, 46(22) 8995-9002 (2013). http:/dx/doi.org/10.1021/ma4013175
  • Raghunandan K. Bhakta, Sean Maharrey, Vitalie Stavila, Aaron Highley, Todd M. Alam, Eric Majzoub, and Mark Allendorf, “Thermodynamics and Kinetics of NaAlH4 Nanocluster Decomposition”, Phys. Chem. Chem. Phys., 14, 8160-8169 (2012).  http://dx.doi.org/10.1039/c2cp40196g
  • Janelle J. Jenkins, Michael R. Hibbs and Todd M. Alam, “Identification of Multiple Diffusion Rates in Mixed Solvent Anion Exchange Membranes Using High Resolution MAS NMR”, ACS Macro Letters, 1, 910-914 (2012).
  • Yu Hou, Todd M. Alam, Mark A. Rodriguez, May Nyman, “Aqueous Compatibility of Group IIIA Monomers and Nb-Polyoxoanions”, ChemComm, 48, 6004-6006 (2012). http://dx.doi.org/10.1039/c2cc31284k
  • Janelle E. Jenkins, Michelle E. Seitz, C. Francisco Buitrago, Karen I. Winey, Kathleen L. Opper, Travis W. Baughman, Kenneth B. Wagener, Todd M. Alam, “The Impact of Zinc Neutralization on the Structure and Dynamics of Precise Polyethylene Acrylic Acid Ionomers: A Solid-State 13C NMR Study”, Polymer,  53, 3917-3927 (2012).  http://dx.doi.org/10.1016/j.polymer.2012.06.019   
  • Todd M. Alam, Muniasamy Neerathilingam, M. Kathleen Alam, David E. Volk, G. A. Shakeel Ansar, Swapna Sarkar and Bruce A Luxon “1H Nuclear Magnetic Resonance (NMR) Metabolomic Study of Chronic Organophosphate Exposure in Rats”, Metabolites, 2(3), 479-495 (2012). http://dx.doi.org/10.3390/metabo2030479
  • Todd M. Alam, Charles J. Pearce, Janelle Jenkins, “Ab Initio Investigation of Sarin Micro-Hydration”, Theor. Chem., 995, 24-35 (2012). http://dx.doi.org/10/1016/j.comptc.2012.06.022
  • Todd M. Alam and Janelle E. Jenkins, “ HR-MAS NMR Spectroscopy in Material Science”, in Advanced Aspects of Spectroscopy, Muhammad Akhyar Farrukh (Ed.), ISBN: 978-953-51-0715-6, InTech, Available from: http://www.intechopen.com/books/advanced-aspects-of-spectroscopy/hr-mas-nmr-spectroscopy-in-material-science (2012).
  • Vitalie Stavila, Raghunandan K. Bhakta, Todd M. Alam, Eric H. Majzoub, and Mark D. Allendorf, “Reversible Hydrogen Storage by NaAlH4 Confined Within a Titanium-Functionalized MOF-74(Mg) Nanoreactor”, ACS Nano, 6(11), 9807-9817 (2012). http://dx.doi.org/10.1021/nn304514c
  • May Nyman and Todd M. Alam, “Dynamics of Uranyl Peroxide Nanocapsules”, J. Am. Chem. Soc., 134, 20131-20138 (2012). http://dx.doi.org/10.1021/ja308673f
  • Todd M. Alam, Janelle E. Jenkins, Dan S. Bolinitineanu, Mark J. Stevens, Amalie L. Frischknecht, C. Francisco Buitrago, Karen I. Winey, Kathleen L. Opper and Kenneth B. Wagener, “Heterogeneous Coordination Environments in Lithium-Neutralized Ionomers Identified Using 1H and 7Li MAS NMR”, Materials, 5, 1508-1527 (2012). http://www.mdpi.com/1996-1944/5/8/1508
  • C. M. Washburn, T. N. Lambert, J. Blecke, D. Davis, P.S. Finnegan, B.G. Hance, D. Wheeler, T.E. Beechem, T.M. Alam, M.T. Brumbach, and J.M. Strong, “Tunable Young’s Modulus in Carbon MEMS using Graphene-based Stiffeners”, ECS Transactions, 50(12), 423-434 (2012), http://dx.doi.org/10.1149/05012.0423ecst
  • May Nyman, Mark A. Rodriguez, Todd M. Alam, “The U28 Nanosphere: What’s Inside?”, European Journal Inorganic Chemistry, 14, 2197-2205 (2011).
  • T. M. Alam, D. Hart, S. L. B. Rempe, “Computing the 7Li NMR Chemical Shielding of Hydrated Li+ using Cluster Calculations and Time-Averaged Configurations from ab initio Molecular Dynamics Simulations”, Physical Chemistry Chemical Physics, 13, 13629-13637 (2011).
  • J. C. Harper, D. M. Lopez, E. C. Larkin, M. K. Economides, S. K. McIntyre, T. M. Alam, M. S. Tartis, M. Werner-Washburne, C. J. Brinker, S. M. Brozik, D. R. Wheeler, “Encapsulation of S. cerevisiae in Poly(glycerol) Silicate Derived Matrices: Effect of Matrix Additives and Cell Metabolic Phase on Long-Term Viability and Rate of Gene Expression”, Chemistry of Materials, 23 (10), 2555-2564, (2011).
  • J. W. Blanchard, J. P. Belieres, T. M. Alam, J. L. Yarger, G. P. Holland, “NMR Determination of the Diffusion Mechanisms in Triethylamine-Based Protic Ionic Liquids”, Journal of Physical Chemistry Letters, 2 (9), 1077-1081 (2011). DOI: 10.1021/jz200357j
  • Todd M. Alam, D.R. Dreyer, C. W. Bielwaski, R. S. Ruoff, “Measuring Molecular Dynamics and Activation Energies for Quaternary Acyclic Ammonium and Cyclic Pyrrolidinium Ionic Liquids using 14N NMR Spectroscopy”, The Journal of Physical Chemistry A, 115 (17), 4307-4316 (2011). http://dx.doi.org/10.1021/jp200630k
  • Jeffery Potts, Sun Lee, Jinho An, Meryl Stoller, Richard Piner, Todd M. Alam, Rodney Ruoff, “Thermomechanical Properties of Poly(methyl Methacrylate)/Chemically Modified Graphene Nanocomposites Made by In Situ Polymerization”, Carbon, 49(8), 2615-2623 (2011).
  • Todd M. Alam, Janelle E. Jenkins, ichelle E. Seitz,  C. Francisco Buitrago, Karen I. Winey, Kathleen L. Opper, Travis W. Baughman and Kenneth B. Wagener“1H MAS NMR Spectroscopy of Polyethylene Acrylic Acid Copolymers and Ionomers”, Chapter 7 in NMR Spectroscopy of Polymers: Innovative Strategies for Complex Macromolecules; edited by H. Cheng et al. ACS Symposium Series, Washington, DC, 115-131 (2011).
  • Jenkins, Janelle E.; Seitz, Michelle E.; Buitrago, C. Francisco; Winey, Karen I.; Opper, Kathleen L.; Baughman, Travis W.; Wagener, Kenneth B.; Todd M. Alam, “Random or precise? Solid-state NMR Structure and Dynamics Characterization of Zinc Neutralized Polyethylene Acrylic Acid Ionomer”, ACS Polymer Preprints, 52(2), 332-333 (2011).
  • Timothy J. Boyle, Leigh Anna M. Steele, Alia M. Saad, Mark A. Rodriguez, Todd M. Alam and Sarah K. McIntyre, “Structural Diversity in a Series of Alkyl-Substituted Cesium Aryloxides”, Inorganic Chemistry, 50, 10363-10370 (2011). dx.doi.org/10.1021/ic201438s.
  • J. Boyle, L. A. M. Ottley, T. M. Alam, M. A. Rodriguez, P. Yang, S. K. McIntyre, “Structural Characterization of Methanol Substituted Lanthanum Halides,” Polyhedron, 29, 1784-1795 (2010).
  • T. M. Alam, M. K. Alam, “Development of Variance-Filtered Instrumental Transfer Methods for High-Resolution NMR Spectroscopy,” Journal of Chemometrics, 24, 261-272. (2010).
  • Michael T. Brumbach, Todd M. Alam, Paul G. Kotula, Bonnie B. McKenzie, Bruce C. Bunker, ACS Applied Materials & Interfaces,2(3), 778-87 (2010).
  • Todd M. Alam, M. Kathleen Alam, Muniasamy Neerathilingam,  David E. Volk, S. Sarkar,  G. A. Shakeel Ansari,  Bruce A. Luxon, “ 1H NMR Metabonomic Study of Rat Response to Tri-Phenyl Phosphate and tri-Butyl Phosphate Exposure”, Metabolomics, 6, 386-394 (2010).
  • Alison L. Costello, Todd M. Alam, “Investigating the Impact of Cholesterol on Magnetically Aligned Sphingomyelin/Cholesterol Multilamellar Vesicles Using 31P NMR”, Chemistry and Physics of Lipids, 163, 506-513 (2010).
  • Neerathilingam, Muniasamy; Volk, David E.; Sarkar, Swapna; Alam, Todd M.; Alam, M. Kathleen; Ansari, G. A. Shakeel; Luxon, Bruce A., “ 1H NMR-Based Metabonomic Investigation of Tributyl Phosphate Exposure in Rats”, Toxicology Letters, 199, 10-16 (2010).
  • Timothy N. Lambert, Claudia C. Luhrs, Carlos A. Chavez, Stephen Wakeland, Michael T. Brumbach, Todd M. Alam, “Graphite Oxide as a Precursor for the Synthesis of Disordered Graphenes Using the Aerosol-Through-Plasma Method”, Carbon, 48, 4081-4089 (2010).
  • May Nyman, Todd M. Alam, Sarah K. McIntyre, Grant C. Bleier, David Ingersoll, “Alternative Approach to Increasing Li Mobility in Li-La-Nb/Ta Garnet Electrolytes”, Chemistry of Materials, 22, 5401-5410 (2010).
  • Jacalyn S. Clawson, Randall T. Cygan, Todd M. Alam, Kevin Leung, Susan B. Rempe, “Ab Initio Study of Hydrogen Storage in Water Clathrates”, J. Computational and Theoretical Nanoscience, 7, 2602-2606 (2010).

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