Functional nanomaterials made easy

Using pressure instead of chemicals, a Sandia team led by Hongyou Fan (1815) has fabricated nanoparticles into nanowire-array structures similar to those that underlie the surfaces of touch-screens for sensors, computers, phones, and TVs. The pressure-based fabrication process takes nanoseconds. Chemistry-based industrial techniques take hours.

The process, called stress-induced fabrication “is a new technology that mimics imprint processes already used by manufacturers,” says Hongyou. “Only instead of embossing credit cards, we’re using the same type of process to fabricate nanowires or other nano-sized components at ultrashort time scales.”

The method, for which three patents have been issued, is nine million times faster than any known chemical method when performed on Sandia’s Veloce pulsed power machine, which generates pressures on the order of 100,000 atmospheres, says colleague Jack Wise (1646).

Less exotically, for manufacturing instead of research, embossing machines similar to those already commercially in use could serve. “It’s conceivable that few modifications would be needed to convert the machines from embossing to fabrication,” Hongyou says.

The Sandia process saves:

• time, because circuits can be fabricated in seconds instead of the hours required by chemical methods;
• the environment, because there’s no chemical waste to clean up;
• materials, because exactly the amount needed is placed on a substrate.

Also, defects common in industrial semiconductor chemical fabrication are reduced in number by the pressure process, which acts to fill any vacancies occurring in the product’s atomic lattice.

“I have never seen or heard of this [process] in our extensive interaction with some of the leading material scientists in the world,” says Tom Brennan of Chicago-based Arch Venture Partners, speaking in a YouTube video about an earlier version of the process. “It allows us to think of completely new material solutions to problems industry is facing across the board.”

https://www.youtube-nocookie.com/embed/kFNTpo1bAHQ?rel=0

That earlier version of the pressure-based process worked by using a hand-tightened vise with diamond anvils, but that tool was not rapid or malleable enough for commercial production. Industrial embossing machines, on the other hand, produce sufficient pressure and are controllable.

“For a touch-screen, the pressure has to be worked out beforehand to stop the compression at just the right distance from the target: not too far, not too close, to produce the underlying nanowiring for a flat screen,” says Hongyou. “It’s a matter of programming the force applied to precisely determine how much to compress.”

That is, for flat screens, the nanowires need to be made flexible enough to contact an electrically charged layer of the device when pressed by a finger, yet far enough apart to remain separate when there’s no signal.

The technology, recently reported in Nature Communications, can fabricate a wide variety of nanoscale components including nanorods and nanosheets. The components can either be organized during their formation or dispersed in solvents for later assembly. The method could be used for chemical sensors, strain detectors, and electrodes in solar cells.

In addition to Hongyou and Jack, paper authors include Kaifu Bian (1815), J. Matthew D. Lane (1814), Gary S. Grest (1131), Tommy Ao (1646), Randy Hickman (1647), and Zhongwu Wang from Cornell University, plus former Sandia post-doctoral fellows Binsong Li and K. Michael Salerno.

The work was supported by DOE’s Office of Science. Part of the work was carried out at the Sandia/Los Alamos-run Center for Integrated Nanotechnologies, a DOE Office of Science User Facility.

Hongyou Fan joins UNM faculty

Sandia researcher Hongyou Fan has been appointed a National Laboratory Professor at the University of New Mexico’s School of Engineering in its Chemical and Biological Engineering Department. The non-tenure-track appointment, which took effect March 1, automatically renews every three years, and was made “in recognition of your significant achievements,” according to UNM’s award notification. “I look forward to the opportunities for development of collaborative programs and student mentoring,” says Hongyou.